Showing 50 of 25357 papers

On the Convergence of Orthogonal Series

V. F. GAPOSHKIN
1964 SovietRxiv: ru-196401.77196

This note studies sufficient coefficient conditions for almost everywhere convergence of orthogonal series, refining the classical Menshov and Rademacher logarithmic criterion. The author introduces a dyadic decomposition method whose subdivision points depend on a functional of the coefficients, yi…

Embedding theorems for some classes of abstract functions

A. H. Gudiev
1964 SovietRxiv: ru-196401.77188

The paper develops embedding theorems for mixed norm and weighted classes of abstract functions obtained by viewing functions on Euclidean space as functions of separate vector variables. It defines analogues of Sobolev, weighted Sobolev, and Besov type spaces with two integrability exponents, inclu…

Mass Spectrometric Study of Intermediate Products of the Interaction of Silicon with Copper Monochloride

S. A. GOLUBTSOV
1964 SovietRxiv: ru-196401.77045

This study examines whether divalent silicon chloride, dichlorosilylene, is formed as an intermediate in the reaction of silicon with cuprous chloride at temperatures relevant to organochlorosilane synthesis. Using a modified MI-1305 mass spectrometer, the authors compared spectra of silicon tetrach…

Some Properties of Ferrocene Diazo Compounds

Academician A. N. Nesmeyanov, V. N. Drozd, V. A. Sazonova,
1964 SovietRxiv: ru-196401.76888

This study examines the chemical properties and reactivity of ferrocenyl diazonium species generated by acidolysis of benzenediazoaminoferrocene, with emphasis on azo coupling, triazene formation, and reactions with active methylene compounds. Low-temperature reactions with phenol, dimethylaniline, …

On the Possibility of Regulating the Degree of Alternation in the Copolymerization of Styrene with 2-Vinylpyridine

Unknown
1964 SovietRxiv: ru-196401.76691

This paper examines whether the alternation tendency in styrene and 2-vinylpyridine copolymerization can be regulated by changing the polarity of the 2-vinylpyridine double bond through hydrogen bonding with proton donor additives. The authors argue that additives of different acidity form complexes…

On Hilbert’s Method for Solving the Boltzmann Kinetic Equation

Corresponding Member of the Academy of Sciences of the USSR V. V. Struminskii
1964 SovietRxiv: ru-196401.76646

This paper examines the applicability of Hilbert’s small-parameter method for solving the kinetic Boltzmann equation and its relation to hydrodynamic approximations. By analyzing the recurrent integral equations and their solvability conditions, it argues that Hilbert’s general formulation yields a …

Form Birefringence in Spherulites and Stretched Polypropylene Films

V. I. Selikhova, G. S. Markova, Academician V. A. Kargin
1964 SovietRxiv: ru-196401.76562

This study examines the origin of positive birefringence in polypropylene spherulites, where molecular chains are oriented nearly perpendicular to the radial fibrils. The authors interpret the observed optical behavior as a combination of negative intrinsic birefringence of polymer chains and form b…

Stereochemistry of the Oxidation of Geometric Isomers of 13-Methyl-7-acetoxy-$\Delta^{4(12)}$-dodecahydrophenanthrene-1,2-dicarboxylic Acid and Their Derivatives

V. F. KUCHEROV, I. A. GURVICH, I. M. MILSHTEIN
1964 SovietRxiv: ru-196401.76532

The study examines the stereochemistry of peracetic acid oxidation of geometric isomers of 13-methyl-7-acetoxy-dodecahydrophenanthrene-1,2-dicarboxylic acids, their diesters, and corresponding anhydrides. Oxidation experiments and subsequent transformations, including saponification to lactone acids…

Galvanostatic Study of the Recharging Processes of Iridium Chloride Complexes

The recharging of chloride complexes of tri- and tetravalent iridium, described by the reaction
1964 SovietRxiv: ru-196401.76523

The study examines the electrochemical recharging of hexachloroiridate complexes, IrCl6 2− and IrCl6 3−, in 1 M hydrochloric acid on a platinum electrode. Using galvanostatic transition-time curves, the authors analyze cathodic and anodic processes, determine diffusion coefficients, and assess wheth…

Synthesis of Hydronaphthacenes Related to Anhydrotetracyclines

![[chemical structures (I) and (II)]]
1964 SovietRxiv: ru-196401.76429

The paper reports synthetic studies aimed at developing rational routes to 5a,6-anhydrotetracyclines, intermediates relevant to the preparation of natural tetracyclines. Starting from substituted ketols, the authors prepare unsaturated ketones, introduce carbon chains by Michael condensation with ma…

ASYMPTOTIC SPLITTING OF THE EQUATIONS OF A CONTROLLED PROCESS UNDER SLOW VARIATION OF THE PARAMETERS OF THE CONTROLLED OBJECT AND OF THE CONTROL SYSTEM

Unknown
1964 SovietRxiv: ru-196401.76310

This note studies the stability-related equations of a linear controlled process when the parameters of both the controlled object and the automatic control system vary slowly in time. Extending earlier work that assumed distinct and well separated eigenvalues, it treats the case in which eigenvalue…

Reaction of tropylium bromide with tertiary butyl alcohol

Z. N. Parnes, G. D. Murr, R. V. Kudryavtsev,
1964 SovietRxiv: ru-196401.76239

The study examines the unexpected reaction of tropylium bromide with tert-butyl alcohol, a tertiary alcohol that was initially expected not to undergo hydride-transfer reactions analogous to those observed with primary and secondary alcohols. Experiments in aqueous and anhydrous tert-butyl alcohol, …

On the existence of subgroups in a finite nonsolvable group

Ya. G. Berkovich
1964 SovietRxiv: ru-196401.76151

This paper studies how restrictions on solvable, noninvariant, Hall, and maximal subgroups constrain the structure of finite nonsolvable groups. It introduces and uses variants of subgroup types \(S\), \(B\), \(C\), \(p\)-decomposability, and a measure of quasinvariance for maximal chains, together …

On the limiting distribution of a certain class of functionals of a sequence of sums of independent random variables

Unknown
1964 SovietRxiv: ru-196401.75920

The paper studies limiting distributions for double-sum functionals of normalized partial sums of independent identically distributed random variables with mean zero and unit variance. Extending results of Skorokhod on one-dimensional functionals, it gives sufficient conditions on a sequence of nonn…

On the absolute convergence of the series of Fourier coefficients

1. The well-known theorem of Bernstein asserts:
1964 SovietRxiv: ru-196401.75898

This note studies the sharpness of Bernstein-type criteria for absolute convergence of Fourier coefficients in arbitrary complete orthonormal systems. Using a factorization argument through the coefficient map into l1, the synthesis map into L2, and multiplier operators, together with the theorem of…

Detection of Atomic Oxygen during the Cool-Flame Oxidation of Carbon Disulfide by Molecular Oxygen

V. V. AZATYAN, Academician of the Academy of Sciences of the Armenian SSR A. B. NALBANDYAN, É. N. SARKISYAN
1964 SovietRxiv: ru-196401.75842

This study investigates active chain centers in the cold-flame oxidation of carbon disulfide by molecular oxygen, focusing on the possible formation of atomic oxygen. Using electron paramagnetic resonance in a jet vacuum apparatus, the authors recorded spectra attributed to oxygen atoms under flame …

Electron-donating properties of the hydroxyl ion

G. V. Fomin, L. A. Blyumenfel’d, B. I. Sukhorukov
1964 SovietRxiv: ru-196401.75757

This study examines whether hydroxyl ions can act not only in acid, base chemistry but also as electron donors toward strong organic electron acceptors. Using electron paramagnetic resonance, potentiometric measurements, and hydrogen peroxide detection, the authors investigated reactions of hydroxid…

On Stable Methods for Summing Fourier Series

Corresponding Member of the Academy of Sciences of the USSR A. N. TIKHONOV
1964 SovietRxiv: ru-196401.75751

The paper studies the stable recovery of a function value from approximate Fourier coefficients in an orthonormal system of eigenfunctions for a second order boundary value problem. Using Tikhonov regularization, it replaces ordinary Fourier summation, which is unstable under errors in the l2 metric…

X-ray Structural Studies of Pepsin

N. E. SHCHKEVER, N. S. ANDREEVA
1964 SovietRxiv: ru-196401.75436

This study examines a monoclinic crystalline modification of porcine pepsin as a potential object for complete X-ray crystallographic structure determination. Pepsin was purified, crystallized from acidic 20 percent ethanol solution by Northrop’s method, mounted in sealed capillaries, and analyzed u…

On Some Completeness Criteria for the System of Root Vectors of a Linear Operator and Summability of Series with Respect to This System

Unknown
1964 SovietRxiv: ru-196401.75297

This note develops criteria for completeness of systems of root vectors of compact-related linear operators in Banach spaces and for Abel-type summability of expansions with respect to these systems. It proves completeness theorems under nuclearity, approximation-number, resolvent, numerical-range, …

Long-lasting afterglow of aqueous solutions of proteins and synthetic polymers irradiated with X-rays

Unknown
1964 SovietRxiv: ru-196401.75131

This paper investigates the long-lived afterglow of aqueous protein and synthetic polymer solutions following X-ray irradiation, motivated by earlier observations of related luminescence after ultraviolet and gamma irradiation. Using a flow-through apparatus with photomultiplier detection, the autho…

Hofmann cleavage of the pyrazoline ring

Unknown
1964 SovietRxiv: ru-196401.75099

This study examines whether quaternary pyrazolinium salts substituted at position 3 can undergo Hofmann cleavage of the pyrazoline ring at a carbon-nitrogen bond, rather than the previously observed nitrogen-nitrogen cleavage leading to aminonitriles. Iodomethylates and iodoethylates of 1,3-dimethyl…

Proof of the Existence of Analytic Functions of Several Variables Not Representable by Linear Superpositions of Continuously Differentiable Functions of Fewer Variables

Unknown
1964 SovietRxiv: ru-196401.75044

The paper proves an existence theorem for bounded analytic functions of two complex variables, real on the real plane, that cannot be represented on a given planar domain as a finite linear superposition of continuous one-variable functions composed with prescribed continuously differentiable functi…

Surface Effect of a Chemical Process

A. A. ZHUKHOVITSKII, V. A. GRIGORYAN, E. MIKHALIK
1964 SovietRxiv: ru-196401.74963

This paper examines conditions under which the free energy of a chemical process can be converted directly into surface energy, producing a change in interfacial area or surface tension. Using the thermodynamics of irreversible processes and Onsager relations, the authors derive a relation between t…

Thermal Stability of Ferrocene

Unknown
1964 SovietRxiv: ru-196401.74843

This paper examines the thermal stability and decomposition behavior of ferrocene vapor under static isothermal conditions between 400 and 470 degrees Celsius. The authors measure decomposition kinetics, pressure changes, gaseous products, and solid residues in sealed ampoules, and compare the effec…

On the Mechanism of Formation of Aryl-Substituted Silacyclopentanes from Organodichlorosilanes, Styrenes, and Lithium. A New Method for the Preparation of Substituted Disilacyclohexanes

Unknown
1964 SovietRxiv: ru-196401.74842

The study examines the mechanism by which aryl-substituted silacyclopentanes form from organodichlorosilanes, styrenes, and lithium, focusing on whether biradical or biionic intermediates are involved. By reducing styrene to an equimolar amount and using tetrahydrofuran diluted with inert hydrocarbo…

Buckling of Shells of Revolution Under Internal Pressure

Corresponding Member of the Academy of Sciences of the USSR A. V. POGORELOV
1964 SovietRxiv: ru-196401.74783

This note investigates the loss of stability of convex shells of revolution under internal pressure, focusing on the formation of localized bulges arranged along a parallel. Using a geometrical approach, it models the deformation energy as concentrated near the boundaries of small elliptical bulging…

Catalytic transformations of $\beta$-furylpropionic and $\beta$-furylacrylic acids during vapor-phase hydrogenation

I. F. Bel’skii, Corresponding Member of the Academy of Sciences of the USSR N. I. Shuikin,
1964 SovietRxiv: ru-196401.74754

This study examines vapor phase catalytic hydrogenation and hydrogenolysis of beta-furylpropionic and beta-furylacrylic acids over platinized carbon, with attention to how temperature and hydrogen availability affect opening of the furan ring and subsequent transformations. Experiments at 250 to 300…

ON SOME PERTURBATIONS OF A CLOSED LINEAR OPERATOR

Unknown
1964 SovietRxiv: ru-196401.74744

The paper studies perturbations of a closed linear operator in a Banach space by bounded operators drawn from a commutative Banach algebra that commute with it. It first proves algebraic stabilization criteria for the intersections of kernels with iterated ranges, showing in particular that stabiliz…

On the adsorption of fatty acids at the solution–air and solution–mercury interfaces

R. I. KAGANOVICH, V. M. GEROVICH, T. G. OSOTOVA
1964 SovietRxiv: ru-196401.74367

This study compares the adsorption activity of a homologous series of fatty acids at solution, air and solution, mercury interfaces, with particular attention to the applicability of Traube’s rule. Adsorption on mercury was examined from electrocapillary curves measured with a Gouy electrometer, whi…

Synthesis of Elements with Multiple Stable States Based on a Nonlinear Two-Port Network with a Nonmonotonic Amplitude Characteristic

Unknown
1964 SovietRxiv: ru-196401.74199

The paper addresses the synthesis of multistable storage elements for digital computing devices using nonlinear four-terminal networks with nonmonotonic amplitude characteristics, aiming to reduce the dependence of circuit complexity on the number of stable states. It formulates the equilibrium cond…

The solution of certain systems of equations in words

Unknown
1964 SovietRxiv: ru-196401.74182

The paper studies systems of equations in words over a fixed alphabet, with variables ranging over words, and addresses Markov’s problem of recognizing whether such a system has a solution. It introduces a formal class of terms built from words, powers, and recursively defined functions, then states…

Explanation of the Saturation of the Drift Velocity of Charge Carriers in Piezoelectric Semiconductors

Unknown
1964 SovietRxiv: ru-196401.74087

This paper addresses the observed saturation of current-carrier drift velocity in piezoelectric semiconductors such as CdS, CdSe, and GaAs when the drift velocity exceeds the speed of sound. It argues that the effect is connected with ultrasonic generation and the resulting acoustoelectric current, …

On the Number-Theoretic Basis of Probabilistic Number Theory

M. B. BARBAN, A. I. VINOGRADOV
1964 SovietRxiv: ru-196401.74082

This note studies estimates underlying probabilistic number theory, especially the second fundamental lemma concerning integers whose component composed of small prime powers exceeds a given bound. Using earlier sieve estimates, the authors derive a sharper bound for this counting function, with dec…

Synthesis of aryl-substituted

AL. SPASOV, B. PANAYOTOVA, EVG. GOLOVINSKII
1964 SovietRxiv: ru-196401.73629

This paper reports the synthesis of aryl-substituted azetidinethiones-2 as sulfur analogues of aryl-substituted azetidinones-2, motivated by possible changes in chemical reactivity and biological activity after replacement of oxygen by sulfur. The authors treated several phenyl-substituted beta-lact…

On the distribution of prime numbers in short progressions $\operatorname{mod}p^n$

M. B. BARBAN, Corresponding Member of the Academy of Sciences of the USSR Yu. V. LINNIK, N. G. CHUDAKOV
1964 SovietRxiv: ru-196401.73593

The paper studies the distribution of prime numbers in arithmetic progressions modulo powers of a fixed prime, \(D=p^n\), a case where sharper results are sought than for general moduli. It proves that, for \(x \gg D^{8/3+\varepsilon}\), primes are asymptotically equidistributed among reduced residu…

A New Method for Obtaining Optically Active Aspartic Acid

Unknown
1964 SovietRxiv: ru-196401.73573

A method is described for preparing optically active aspartic acid through the addition of optically active alpha-phenylethylamine to maleic acid, followed by conversion of the resulting salts to N-phenylethylaminosuccinic acids and catalytic hydrogenation. The reaction gives separable crystalline f…

On the Beam Instability of a Rarefied Inhomogeneous Plasma

V. V. Arsenin
1964 SovietRxiv: ru-196401.73522

This paper analyzes short wavelength instabilities localized at inhomogeneous boundaries in rarefied magnetized plasma, focusing on finite width ion beams whose edge gradients may be comparable to the ion Larmor radius. Starting from linearized collisionless kinetic equations with a self consistent …

Electrocapillary Curves of Liquid Nitrogen

Academician A. N. FRUMKIN, N. S. POLYANOVSKAYA, N. B. GRIGOR’EV
1964 SovietRxiv: ru-196401.73458

Electrocapillary behavior of liquid gallium was investigated using a reduced Gouy capillary electrometer with high-purity metal, with measurements in acidic, neutral, and alkaline electrolyte solutions chosen to avoid oxide-film formation and hydrogen evolution. The resulting electrocapillary curves…