Showing 50 of 25357 papers

Theory of thermomolecular pressure difference and thermal transpiration (thermo-osmosis) of gases in moderately wide capillaries

Corresponding Member of the Academy of Sciences of the USSR B. V. DERYAGIN, Yu. I. YALAMOV
1964 SovietRxiv: ru-196401.80222

The paper develops a theory of thermomolecular pressure difference and thermal transpiration of gases in moderately wide capillaries, extending an earlier Chapman-Enskog based treatment for the limiting case of small Knudsen number. Using Onsager relations, the Navier-Stokes equation with a slip bou…

INVESTIGATION OF GAS FLOWS BY ELECTRON-BEAM METHODS

This article considers the question of determining the velocity and density of a gas by electron-beam methods.
1964 SovietRxiv: ru-196401.79950

This paper surveys electron beam techniques for measuring and visualizing gas flows, focusing on local velocity and density determination in cold gases and plasmas. It describes fluorescent marking for gases with long afterglow, Doppler shifts of electron excited fluorescence for short afterglow gas…

On a Model in the Theory of Superconductivity

Unknown
1964 SovietRxiv: ru-196401.79904

This paper proposes a generalization of the Bardeen, Cooper, Schrieffer superconductivity model intended to allow an isotropic excitation spectrum in Fermi systems where attraction may occur in higher angular harmonics, such as liquid helium-3. The model replaces ordinary Cooper pairing by pairings …

On the Features of the Kinetics of the Polymorphic Transformation of Zirconium Dioxide during Cooling

Unknown
1964 SovietRxiv: ru-196401.79747

This paper examines the kinetics of diffusionless polymorphic transformations in zirconium dioxide during cooling, focusing on the relation between isothermal and athermal martensitic behavior. Using X-ray observations of high-purity zirconia and metastable tetragonal zirconia obtained from zirconiu…

Three Types of Abstract Integrals

Unknown
1964 SovietRxiv: ru-196401.79724

Tolstov develops a classification of formal differentiation and the abstract integrals it generates by adding supplementary axioms to a previously defined general scheme. The paper distinguishes weak, medium, and strong differentiation, corresponding to integrals of Duhamel, Daniell, and Lebesgue ty…

Phase Equilibrium Diagram of the Chromium–Osmium System

Unknown
1964 SovietRxiv: ru-196401.79580

The study determines the phase equilibrium diagram of the chromium, osmium system, for which previous work had established two intermetallic compounds and substantial mutual solubility. Alloys of selected compositions were prepared by arc melting, homogenized and annealed at several temperatures, th…

Investigation of the ion-exchange system $\mathrm{H}\dot{\vphantom{v}}$ , $\mathrm{Ca}\ddot{\vphantom{v}}\parallel\mathrm{R}'$, $\mathrm{Cl}'$ – $\mathrm{H}_2\mathrm{O}$ by the ray method

Corresponding Member of the Academy of Sciences of the USSR A. V. NIKOLAEV, V. L. BOGATYREV, A. I. VULIKH
1964 SovietRxiv: ru-196401.79524

The study examines hydrogen and calcium ion exchange on the KU-2 cation exchanger in concentrated hydrochloric acid and calcium chloride solutions, a region relevant to water deionization but less characterized than dilute systems. Using a ray method of physicochemical analysis at 25 degrees C, the …

Interaction of $\mathrm{Nd}_2\mathrm{O}_3$ with Water

Unknown
1964 SovietRxiv: ru-196401.79229

This study examines the interaction of neodymium oxide with water vapor and liquid water, with attention to the stability, composition, and structure of hydrated phases. Using hydrothermal synthesis, controlled humidity experiments, thermogravimetry, thermal analysis, infrared spectroscopy, X-ray di…

Measurement of Atomic Oxygen and Hydrogen Concentrations in a Rarefied Hydrogen Flame by the EPR Method

V. P. Balakhnin, Yu. M. Gershenzon, Academician V. N. Kondrat’ev,
1964 SovietRxiv: ru-196401.79225

This study investigates atomic oxygen and hydrogen in rarefied hydrogen flames, motivated by uncertainties in the elementary rate constants governing chain propagation and branching. Using an electron paramagnetic resonance jet apparatus with the reactor placed directly in the resonator, the authors…

On the Cohomology of the Steenrod Algebra

Unknown
1964 SovietRxiv: ru-196401.79101

The paper studies the cohomology algebra of the mod 2 Steenrod algebra as it appears in the Adams spectral sequence for stable homotopy groups of spheres. It constructs a spectral sequence converging to this cohomology algebra, with a polynomial first term, and develops the use of spectral cohomolog…

General Methods of “Increasing Multipliers” and Approximation of Unbounded Continuous Functions by Some Specific Polynomial Operators

Unknown
1964 SovietRxiv: ru-196401.79057

The paper develops a general method of multiplier enlargement for linear positive operators in Banach spaces and applies it to polynomial approximation of unbounded continuous functions. A convergence theorem is proved under normalization and singularity conditions, then used to construct and analyz…

Selenium-containing derivatives of acrylic and methacrylic acids

A. N. Pudovik, E. I. Kashevarova
1964 SovietRxiv: ru-196401.78950

This paper reports the preparation and characterization of selenium-containing derivatives of acrylic and methacrylic acids, a class for which the authors note little prior information. Selenophenol was reacted with methacryloyl chloride in ether in the presence of triethylamine, giving selenophenyl…

A New Crystalline Modification of Yttrium Orthosilicate with the Garnet Structure

Corresponding Member of the Academy of Sciences of the USSR N. A. TOROPOV, I. A. BONDAR,
1964 SovietRxiv: ru-196401.78918

This paper reports the preparation and characterization of a new crystalline modification of yttrium orthosilicate with composition Y4Si3O12, obtained as single crystals from a potassium fluoride melt. Goniometric, chemical, optical, thermal, hardness, and X-ray diffraction studies show that this fo…

Phosphine derivatives of amino acids and peptides

Unknown
1964 SovietRxiv: ru-196401.78901

This paper reports the synthesis of phosphinic derivatives of alpha-amino acids and peptide analogs motivated by the biological activity of organophosphorus compounds and the potential significance of phosphinic amino acid analogs. Using the mixed anhydride method, carbobenzoxy-protected glycine, al…

Infrared Spectra and Structure of Aromatic Carbonium Ions

D. S. BYSTROV
1964 SovietRxiv: ru-196401.78884

This paper investigates the structure of aromatic carbonium ions formed as sigma complexes of aromatic hydrocarbons with hydrogen bromide and aluminum bromide, using low-temperature infrared spectroscopy. Spectra of complexes of benzene, toluene, mesitylene, hexamethylbenzene, and related hydrocarbo…

Adsorption of Vapor Mixtures and the Structure of Adsorbents

B. P. Bering, V. V. Serpinsky, S. I. Surinova
1964 SovietRxiv: ru-196401.78883

This paper analyzes adsorption of binary vapor mixtures on solid adsorbents as a means of relating sorption behavior to pore structure. Using curves that plot adsorption of the more strongly adsorbed component against that of the less strongly adsorbed component at constant vapor composition, the au…

Approximation Properties of Subspaces of Finite Codimension in the Space of Continuous Functions

A. L. GARKAVI
1964 SovietRxiv: ru-196401.78846

The paper studies finite codimensional subspaces of the space of continuous functions on a bicompact space and gives criteria for proximinality, uniqueness of best approximation, and the Chebyshev property. Using the annihilator of the subspace, represented by finite systems of regular measures, it …

Electron microscopic study of structural changes occurring during thermal vulcanization of chloroprene rubbers

V. G. KALASHNIKOVA, M. V. KAZHDAN, Z. Ya. BERESTNEVA,
1964 SovietRxiv: ru-196401.78789

This study examines how thermal vulcanization affects supramolecular ordering and crystallization in chloroprene rubbers, using nairit A and neoprene AC films observed by electron microscopy. Films were vulcanized at 153 degrees in air or vacuum for varying times, and network density was estimated b…

Energy Spectra of a Plasma Interacting with a Transverse Magnetic Field

Academician of the Academy of Sciences of the Ukrainian SSR K. D. SINELNIKOV
1964 SovietRxiv: ru-196401.78765

This paper examines the energy and mass spectra of ions in plasma bunches interacting with a transverse magnetic field, addressing whether previously observed increases in velocity along the field reflect true acceleration or changes in plasma composition. Using electrostatic energy analysis and tim…

Equilibrium of a Plasma Pinch with Helical Perturbations

Unknown
1964 SovietRxiv: ru-196401.78754

This paper examines how static helical perturbations affect the equilibrium of cylindrical plasma columns with nested magnetic surfaces, especially near surfaces whose unperturbed field lines close with the perturbation pitch. By analyzing the helical magnetic-surface integral and the equilibrium eq…

Structure and features of proton NMR spectra of phosphacyclopentene derivatives with unsymmetrically arranged substituents in the ring

Unknown
1964 SovietRxiv: ru-196401.78731

This study examines the structures of phosphacyclopentene derivatives obtained from isoprene, where asymmetric substitution in the ring permits several possible positions of the double bond. Proton NMR spectra and phosphorus decoupling by double nuclear resonance were used to identify ethylenic and …

Effect of $\gamma$-radiation on glucosamine

Corresponding Member of the Academy of Sciences of the USSR N. K. KOCHETKOV, L. I. KUDRYASHOV,
1964 SovietRxiv: ru-196401.78686

This study examines the radiolysis of glucosamine in oxygen-free aqueous solution under cobalt-60 gamma irradiation, motivated by the biological importance of amino sugars and the lack of prior radiation-chemical data for this class. The authors develop a paper-chromatographic micromethod, combined …

On Some Features of the Gas-Phase Oxidation of Hydrocarbons on Copper Catalysts

N. I. Popova, B. V. Kabakova, F. A. Milman, E. E. Vermel
1964 SovietRxiv: ru-196401.78635

This study examines gas-phase oxidation of unsaturated and aromatic hydrocarbons, and methallyl chloride, over copper catalysts supported on silica, including modified catalysts with heavy-metal oxide or salt additives. Using flow experiments under kinetic conditions with short contact times, the au…

Polymerization of Some Olefin and Vinyl Monomers on Diethylbut-1-en-1-ylaluminum in the Presence of Titanium Halides

Table 1
1964 SovietRxiv: ru-196401.78457

This paper examines the catalytic behavior of diethylbuten-1-yl-1-aluminum in the polymerization of olefinic and vinyl monomers, with attention to its intermediate properties between trialkylaluminum compounds and their halogen or oxy derivatives. Experiments with ethylene, propylene, styrene, vinyl…

Cardinalities of bases of an $H$-closed space

In this note I shall prove
1964 SovietRxiv: ru-196401.78449

The note studies cardinality bounds for pseudobases in compactness-like topological spaces. It proves that if an H-closed space has a t-pseudobase such that, at each point, the family of pseudobase elements for which the point is a contact point has cardinality at most a, then the whole t-pseudobase…

On positional operatives

L. M. GLUSKIN
1964 SovietRxiv: ru-196401.78291

The paper studies n-ary algebras, called n-operatives, whose single operation satisfies generalized associativity, alternativity, commutativity, or positional permutation identities. It develops notions of one-sided and two-sided invertibility, ideals, unitary elements, and identities, and proves st…

Kinetics of the acidolysis of symmetric aromatic and aliphatic mercury compounds

Academician A. N. NESMEYANOV, A. E. BORISOV, I. S. SAVEL’EVA
1964 SovietRxiv: ru-196401.78235

The study examines the kinetics of hydrochloric acidolysis of symmetrical aromatic, aliphatic, and unsaturated organomercury compounds in 90% aqueous dioxane, with reaction rates measured acidimetrically and compared with isolated products. All investigated reactions were second order, and substitue…

On the Effect of Temperature on the Structural Selectivity of Diene Synthesis

V. F. Kucherov, A. S. Onishchenko, B. A. Rudenko, E. A. Elperina
1964 SovietRxiv: ru-196401.77951

This study reexamines how temperature affects the structural orientation of Diels Alder condensation of isoprene with acrylic type dienophiles, focusing on the formation of para and meta adducts. Equimolar reactants in benzene were heated at several temperatures, and the isomeric composition of prod…

On monotone entire functions of finite degree

B. A. RYMARENKO
1964 SovietRxiv: ru-196401.77926

This paper studies extremal problems for bounded monotone entire functions of finite degree that are real on the real axis and satisfy one or two prescribed linear conditions. It proves that, for up to two admissible constraints, an extremal function of minimal uniform norm may be chosen so that its…

On the Determination of the Concentration Dependence of Certain Thermodynamic Functions of Ferrite Solid Solutions

Corresponding Member of the Academy of Sciences of the USSR G. I. CHUFAROV
1964 SovietRxiv: ru-196401.77904

This paper examines how the concentration dependence of thermodynamic functions can be estimated for ferrite solid solutions with spinel structure, using the copper ferrite and magnetite system as the main example. It derives configurational expressions for entropy and internal energy of mixing base…

On the Theory of Quadratic Pencils of Self-Adjoint Operators

M. G. KREIN, G. K. LANGER
1964 SovietRxiv: ru-196401.77856

This paper studies spectral properties of quadratic operator pencils of the form L(lambda) = lambda squared I + lambda B + C in a Hilbert space, with B self-adjoint and C subject to compactness, positivity, or damping assumptions. The authors develop an approach based on the associated quadratic ope…

EPR Evidence for the Participation of the Trapped Electron in Radiation-Chemical Reactions in Frozen Aqueous Solutions

B. G. ERSHOV, A. K. PIKAEV, P. Ya. GLAZUNOV,
1964 SovietRxiv: ru-196401.77848

Electron paramagnetic resonance was used to examine radicals formed by irradiation of frozen aqueous sodium nitrite and sodium nitrate solutions in acidic, neutral, and alkaline media. By comparing spectra during warming and varying alkali and solute concentrations, the study assigns observed signal…

A New Method for the Preparation of Alkyldichlorogermanes and Alkyltrichlorogermanes

V. F. MIRONOV, A. L. KRAVCHENKO
1964 SovietRxiv: ru-196401.77792

A preparative method is described for alkylating trichlorogermane to obtain alkyldichlorogermanes, compounds previously difficult to access by known routes and not obtainable from trichlorogermane with Grignard or organolithium reagents. The study examines reactions of trichlorogermane, especially i…

On the Catalytic Properties of Radioactive Tungsten Disulfide in the Dehydration Reaction of n-Decyl Alcohol

Academician Vikt. I. Spitsyn, V. I. Pikaeva, I. E. Mikhailenko
1964 SovietRxiv: ru-196401.77744

This paper examines how incorporation of radioactive sulfur 35 affects the catalytic properties of tungsten disulfide, a semiconductor catalyst, in the vapor phase dehydration of n-decyl alcohol. Nonradioactive and radioactive tungsten disulfide samples were synthesized from tungsten and sulfur, cha…

Application of the Polarographic Method for Determining the Molecular Weight of Polyvinyl Alcohol

V. D. BEZUGLYI, E. K. SALIICHUK
1964 SovietRxiv: ru-196401.77722

This paper examines the use of polarographic maxima for determining the molecular weight of polyvinyl alcohol. The authors measure suppression of the second-kind polarographic maximum on the copper wave in potassium chloride solution for fractions of polyvinyl alcohol with different molecular weight…

Investigation of the structure of surface compounds formed during ethanol adsorption on $\gamma$ -aluminum oxide by infrared absorption spectroscopy

Corresponding Member of the USSR Academy of Sciences G. K. Boreskov, Yu. M. Shchekochikhin,
1964 SovietRxiv: ru-196401.77541

This study uses infrared absorption spectroscopy to examine surface compounds formed when ethanol is adsorbed on gamma alumina at different temperatures. The spectra indicate physically adsorbed ethanol at low temperature, two types of surface ethoxy groups formed through reaction with surface hydro…

DIFFRACTION LOSSES AND RESONANT TYPES OF OSCILLATIONS IN OPEN RESONATORS WITH CYLINDRICAL MIRRORS

V. Ya. Balakhanov, V. K. Zhivotov, A. R. Striganov
1964 SovietRxiv: ru-196401.77529

This paper reports a microwave experimental study of open resonators with cylindrical mirrors, motivated by their use in quantum generators, dielectric studies, and plasma diagnostics. Using an 8 mm Fabry-Perot type interferometer with silvered cylindrical mirrors, the authors measured quality facto…