Showing 50 of 25357 papers

Heats of chemisorption of oxygen on silver and their change upon introduction of sulfur onto the surface

Unknown
1965 SovietRxiv: ru-196501.17523

Direct calorimetric measurements were used to determine differential heats of oxygen adsorption on porous silver at 110°C and to examine how small amounts of chemisorbed sulfur alter these heats. Silver samples were pretreated with hydrogen, oxygen was admitted in small portions, and sulfur was intr…

Coordination sensitivity of the frequency of amino group fan vibrations in the spectra of cyclic ethylenediamine complexes

Academician A. A. GRINBERG, Yu. S. VARSHAVSKII
1965 SovietRxiv: ru-196501.17428

This paper examines the coordination sensitivity of amino-group wagging vibrations in infrared spectra of cyclic ethylenediamine complexes. Extending an earlier argument for ammonia complexes, it relates increases in the wagging frequency to fixation of the nitrogen lone pair by metal coordination, …

On the Mechanism of the Synergistic Effect of Inhibitor Mixtures in Liquid-Phase Oxidation Reactions

Unknown
1965 SovietRxiv: ru-196501.16997

This paper examines the mechanism of synergistic inhibition in liquid-phase oxidation when both inhibitors are capable of reacting with chain-carrying radicals. Using initiated ethylbenzene oxidation at 70 degrees, the authors measured oxygen absorption and inhibitor consumption for mixtures of an a…

CORRELATION OF THE MEAN FREQUENCY OF NUCLEAR QUADRUPOLE RESONANCE WITH THE INDUCTION CONSTANT OF SUBSTITUENTS IN ORGANYLCHLOROSILANES

I. P. Biryukov, M. G. Voronkov, I. A. Safin
1965 SovietRxiv: ru-196501.16939

The paper examines whether the mean chlorine-35 nuclear quadrupole resonance frequency at 77 K can quantify inductive substituent effects in organylchlorosilanes. Using published and measured NQR data for compounds of the RSiCl3, RR'SiCl2, and RR'R''SiCl series, the authors correlate mean resonance …

Study of the Vibrational Spectra of $\mathrm{Be}(\mathrm{NH}_3)_4^{2+}$ and $\mathrm{Be}(\mathrm{H}_2\mathrm{O})_4^{2+}$

Unknown
1965 SovietRxiv: ru-196501.16938

The study examines vibrational spectra of tetrahedral beryllium complex ions Be(NH3)4 2+ and Be(H2O)4 2+ in crystalline tetraammine beryllium chloride and beryllium sulfate tetrahydrate, with additional isotope substitution using deuterated ammonia and water. Infrared absorption and Raman spectra ar…

APPROXIMATIONS OF “FREE” AND “BOUND” CHARGES FOR A SYSTEM OF CHARGED PARTICLES. SELF-CONSISTENT EQUATIONS FOR SECOND DISTRIBUTION FUNCTIONS

Yu. L. Klimontovich
1965 SovietRxiv: ru-196501.16826

The paper develops self-consistent descriptions of charged-particle systems that include both “free” charges, for which correlations are neglected, and “bound” charges, where electron-ion pairing is important, as in weakly ionized hydrogen plasma. Starting from microscopic Liouville and field equati…

The integral operator method in the hereditary theory of creep

M. I. Rozovskii
1965 SovietRxiv: ru-196501.16816

The paper develops an integral operator approach for hereditary creep problems using Volterra operators with Rabotnov type kernels. It reviews known algebraic and differentiation properties of these operators and proves, by induction, a formula expressing products of arbitrary powers of operators wi…

ON THE PROBLEM OF THE OBLIQUE DERIVATIVE

The note is devoted to the following boundary-value problem:
1965 SovietRxiv: ru-196501.16786

This note studies an oblique derivative boundary value problem for harmonic functions in the unit ball, with Hölder continuous coefficients on the sphere depending on \(x^2+y^2\) and \(z\). By expanding the solution and boundary data in angular Fourier series, the problem is reduced to a family of t…

Some Aspects of the Interpretation and Use of Cloud Cover Data Obtained from Meteorological Satellites

Unknown
1965 SovietRxiv: ru-196501.16657

This paper examines how satellite-derived cloudiness fields can be used to infer dynamical meteorological quantities in regions with sparse conventional observations. It proposes a regression method relating Fourier coefficients of total cloud amount to geostrophic vorticity, then uses Poisson equat…

LOW-TEMPERATURE SPECTRAL DISTRIBUTION OF THE INTERNAL PHOTOEFFECT OF CADMIUM SELENIDE AND CADMIUM SULFIDE

V. V. Sobolev
1965 SovietRxiv: ru-196501.16451

This study investigates the low-temperature spectral distribution of the internal photoeffect in CdSe and CdS single crystals, with emphasis on testing excitonic explanations of photosensitivity near the long-wavelength edge of fundamental absorption. Using polarized-light photocurrent measurements …

Thermochemical Determination of the Stabilization Energy of a Quasiaromatic Ring with an $\mathrm{H}$-Bond

M. P. KUZINA, D. N. SHIGORIN, A. P. SKOLDINOV, S. M. SKURATOV
1965 SovietRxiv: ru-196501.16308

This paper determines the stabilization energy of a quasiaromatic six-membered ring formed through intramolecular hydrogen bonding and electron delocalization in the enol form of dibenzoylmethane. The authors measured the heats of combustion of dibenzoylmethane and the ethyl ether of its enolic form…

Crystal structure of $\mathrm{Na}$-orthofluoroberyllate $\gamma$-$\mathrm{Na}_2\mathrm{BeF}_4$

G. G. Guseinov, V. V. Ilyukhin, Academician N. V. Belov
1965 SovietRxiv: ru-196501.16261

The paper reports a single-crystal X-ray determination of the structure of orthorhombic gamma-Na2BeF4, undertaken because this compound was expected to model gamma-Ca2SiO4 and direct structural data had been lacking. Using limited zero-level diffraction photographs, Patterson analysis, and compariso…

ON THE NONUNIQUENESS OF STATIONARY SOLUTIONS FOR A SYSTEM OF EQUATIONS OF THE THEORY OF COMBUSTION WITH PIECEWISE CONSTANT RATE CONSTANT AND COEFFICIENTS OF THERMAL CONDUCTIVITY AND DIFFUSION

Unknown
1965 SovietRxiv: ru-196501.16243

This paper studies stationary one-dimensional combustion waves governed by a nonlinear temperature and concentration system with cut-off reaction rate and piecewise constant thermal conductivity and diffusion coefficients. Building on earlier uniqueness results for constant coefficients when the con…

2-Arylamino-4-phenyl-5-benzoylthiazoles

Unknown
1965 SovietRxiv: ru-196501.16188

A series of 2-arylamino-4-phenyl-5-benzoylthiazoles was prepared by reacting dibenzoylbromomethane with potassium thiocyanate in ethanol in the presence of aromatic amines, giving the target thiazoles in moderate to good yields. The structure of the anilino derivative was confirmed by independent sy…

APPLICATION OF THE \((n, 2n)\) REACTION

I. N. Plaksin, L. P. Starchik, V. T. Tustanovskii
1965 SovietRxiv: ru-196501.15996

This paper examines rapid activation analysis of praseodymium and neodymium in rare-earth materials using 14 MeV neutrons and the dominant inelastic (n,2n) reaction. The authors argue that this approach reduces problems associated with slow-neutron capture analysis, especially self-shielding by elem…

Low-Temperature Ignition of Combustible Gas Mixtures

T. A. Ponizko, A. I. Rozlovskii
1965 SovietRxiv: ru-196501.15938

This study examines low-temperature ignition of combustible gas and vapor mixtures brought into contact with heated solid bodies under free-convection conditions, with attention to whether nonthermal autocatalytic processes can lower ignition temperatures. Experiments in thermostated explosion chamb…

On a class of preimages of metric spaces

Unknown
1965 SovietRxiv: ru-196501.15935

The paper studies spaces that admit, for each open cover, weak mappings into metric spaces, where point preimages are contained in elements of the cover, and relates these spaces to inverse spectra of metric spaces. It gives necessary and sufficient conditions for the existence of such mappings in t…

Polarization-Diffractometric Study of the Formation of a Supramolecular Structure in a Solution of a Helical Polypeptide

V. G. BARANOV, T. I. VOLKOV, S. Ya. FRENKEL
1965 SovietRxiv: ru-196501.15848

This study examines the formation of supramolecular structure in solutions of the helical polypeptide poly-gamma-benzyl-L-glutamate in dioxane using small-angle scattering of polarized light, with parallel microscopic observation. The authors follow concentration- and time-dependent ordering, findin…

Comparative Study of the Electrical and Thermal Properties of Single Crystals and Pressed Samples of Lead Sulfide

Unknown
1965 SovietRxiv: ru-196501.15557

This study compares the electrical and thermal properties of electronic-conducting lead sulfide in single-crystal and pressed polycrystalline forms at room temperature. Single crystals were grown from the melt, pressed specimens were prepared from ground crystals and annealed, and electrical conduct…

ELECTRON PARAMAGNETIC RESONANCE OF MANGANESE IONS IN THE GLASSY As—Se—Ge SYSTEM

L. D. Bogomolova, V. N. Lazukin, I. V. Chepeleva, L. A. Bal'skaya
1965 SovietRxiv: ru-196501.15516

This paper investigates electron paramagnetic resonance spectra of manganese impurities in As, Se, Ge chalcogenide glasses with relatively high germanium contents. Glasses containing 1 at.% Mn were synthesized and measured at 293 and 77 K, with additional temperature dependent observations, to relat…

ILLUMINATION OF A BUBBLE CHAMBER BY MEANS OF A RUBY OPTICAL GENERATOR

V. M. Gorbunkov, V. V. Korobkin, A. M. Leontovich
1965 SovietRxiv: ru-196501.15506

This paper examines the use of a ruby optical generator as a high brightness pulsed illumination source for bubble chamber photography. The authors describe an autocollimation illumination and photographic arrangement using a ruby laser with a concentric resonator, then test it on a glass bubble mod…

Loss of Stability of Shells of Revolution under Torsion

Unknown
1965 SovietRxiv: ru-196501.15461

This paper analyzes the torsional loss of stability of a strictly convex shell of revolution subjected to a moment produced by uniformly distributed tangential edge forces. Using a postcritical approximation in which the deformation is treated as nearly isometric and the elastic energy is concentrat…

Detection of Excited Hydrogen Line Radio Emission in the NGC 6618 (Omega) Nebula

R. L. SOROCHENKO, E. V. BORODZICH
1965 SovietRxiv: ru-196501.15329

This paper reports radio observations aimed at detecting emission from an excited hydrogen recombination line in the HII region NGC 6618, the Omega Nebula, corresponding to transitions between principal quantum levels 91 and 90. Using a 22-meter radio telescope and a null spectral radiometer near 88…

Information about the Samarkand Symposium

I. Kukles
1965 SovietRxiv: ru-196501.15258

This chronicle reports on the inter-university symposium on the qualitative theory of differential equations and its applications, held in Samarkand in October 1964. It summarizes the organization of the meeting, its three thematic sections, and the principal plenary reports on singular points in mu…

A New Pathway for Stereospecific Cyclization of Isoprenoids

=========
1965 SovietRxiv: ru-196501.15096

This study examines acid-catalyzed cyclization of alpha- and beta-monocyclofarnesylacetones as a route to stereospecific formation of polycyclic isoprenoid derivatives. Using infrared and NMR spectroscopy, gas-liquid chromatography, and preparative isolation, the authors show that the alpha isomer g…

Addressing Method Using Compressed Word Codes as Memory Addresses

Unknown
1965 SovietRxiv: ru-196501.15012

This paper describes an addressing method for machine dictionaries in which compressed word codes are used directly as random-access memory addresses. It outlines a letter-by-letter compression procedure based on shifted modulo-2 addition of letter codes chosen with regard to probabilistic and stati…

Nonlinear parabolic equations which have nondivergent form

===========
1965 SovietRxiv: ru-196501.14988

This paper studies nonlinear parabolic equations in nondivergence form on a space-time rectangle, with boundary and initial conditions formulated in Sobolev-type spaces. Using Galerkin approximations, a priori estimates, monotonicity arguments, and compactness results, it proves homeomorphism theore…

On the Statistical Theory of Particle Acceleration by Magnetohydrodynamic Waves in a Weakly Turbulent Rarefied Plasma

Unknown
1965 SovietRxiv: ru-196501.14788

This paper develops a statistical theory for acceleration of fast charged particles by weak, stationary magnetohydrodynamic turbulence in a rarefied plasma, focusing on low-frequency Alfvén waves propagating nearly along a background magnetic field. Using classical perturbation theory applied to the…

On the Nature of the Amplitude-Frequency Curves of an Electromagnetic Vibrator Operating from a Pulsating Current Source

Yu. Ya. Kovyilin
1965 SovietRxiv: ru-196501.14615

This paper examines the amplitude and frequency behavior of a single-stroke electromagnetic vibrator with bias magnetization when driven by a pulsating current source, focusing on near-resonance regimes where common small-displacement approximations are inadequate. Starting from the nonlinear equati…

Plastic Deformation of Steel under Complex Loading

V. I. Maksak
1965 SovietRxiv: ru-196501.14614

This paper reports experiments on plastic deformation of thin-walled steel 40 tubular specimens subjected to combined axial force, internal pressure, and torque. For loading programs with constant stress intensity but different rotations and ratios of principal stresses, the strain intensity increas…

Investigation of the Properties of Cast High-Speed Steels

G. V. BYCHKOV, V. P. SABUROV
1965 SovietRxiv: ru-196501.14613

This study examines crystallization, cooling behavior, electrical resistivity, and linear dimensional changes in cast high-speed steels of P9 and P18 types with varying aluminum additions. The authors melted steels in an induction furnace, cast cylindrical specimens in a dry cast-iron mold, and auto…

Stress State During Shear Chip Formation

M. G. Goldshmidt, G. D. Del, G. L. Kufarev
1965 SovietRxiv: ru-196501.14612

This paper investigates the stress state in the cutting zone during shear chip formation, a problem difficult to address experimentally because of the small size and steep stress gradients of the plastic region. The authors develop and apply a hardness based method, using microhardness distributions…

Centrifugal Casting in Metal Molds of Replaceable Cutting Elements for Tie-Cutting Saws

G. V. Simonov, K. A. Leikhtling, L. S. Smorgon
1965 SovietRxiv: ru-196501.14611

This paper investigates the production of replaceable cutting elements for sleeper-cutting circular saws using centrifugal casting in metal molds, as an alternative to investment casting and lower-wear steels. The authors designed a four-cavity quick-release mold, cast R9 high-speed steel under vari…

Design of a Hand-Held Pneumatic Hammer with Vibration-Damping Devices

Yu. A. Oparin, V. F. Gorbunov, V. I. Baburov
1965 SovietRxiv: ru-196501.14610

This paper presents the design and laboratory evaluation of a hand-held pneumatic chipping hammer intended to reduce occupational vibration exposure. The proposed MPV-series design separates the handle from the barrel with a conical spring, uses a vibration-damping bushing with rubber sleeves to sof…

Method for Calculating Forces in the End Windings of a Single-Layer Winding Using an Electronic Digital Computer

A. I. Verkhoturov, G. A. Sipailov, K. A. Khorkov
1965 SovietRxiv: ru-196501.14609

This paper presents a computational method for determining electrodynamic forces in the end windings of single-layer concentric stator windings, especially under severe transient conditions such as sudden short circuits in surge generators. The authors divide the end winding into geometric zones, de…