Showing 50 of 25456 papers

Experimental Data on the Spectroscopy of Polyatomic Molecules*

R. Mecca
1934 SovietRxiv: ru-193401.34686

This report will discuss experimental data from the spectroscopy of polyatomic molecules, but this by no means implies that research in this field can be considered in any sense complete. The study of the spectra of polyatomic molecules, in contrast to the study of the spectra of diatomic molecules,…

RECENT RESEARCH IN THE FIELD OF THE EXTERNAL PHOTOELECTRIC EFFECT

L. B. Linford
1934 SovietRxiv: ru-193401.16972

The proposed article is an abridged translation of Linford’s review. This review is divided mainly into two parts, the first of which is devoted to general theories of the external photoelectric effect, while the second describes phenomena of a more specialized nature, the interpretation of which li…

On the Method for Obtaining Cinnamic Acid

L. N. Dyakonova-Schultz
1934 SovietRxiv: ru-193401.07657

This study examines modifications of the Perkin reaction for preparing cinnamic acid, with the aim of shortening heating time and improving yield. Experiments varied the acetate or potash reagent, molar ratios of benzaldehyde, acetic anhydride, and base, reaction temperature, and heating duration, f…

On the Mechanism of the Perkin Reaction

L. N. D’yakonova-Shul’ts
1934 SovietRxiv: ru-193401.07655

This paper reviews competing explanations of the Perkin reaction, especially the formation of cinnamic acid from benzaldehyde, acetic anhydride, and acetate salts. It compares earlier experimental interpretations that assign the key condensation either to the aldehyde and anhydride, the aldehyde and…

Determination of the Activity of Hydrogen in Organic Compounds by the Electromotive Force of the Reaction with Sodium

B. V. Tronov and L. P. Kulev
1934 SovietRxiv: ru-193401.07653

This study proposes an electromotive force method for comparing the activity or mobility of hydrogen in organic compounds during reaction with metallic sodium. The authors measured maximum initial EMF values for 52 compounds, chiefly alcohols in benzene solution and, where necessary, without solvent…

Activity of Halogens in Some Derivatives of Benzene Hydrocarbons with a Halogen in the Side Chain

B. V. Tronov and N. Kh. Sibgatullin
1934 SovietRxiv: ru-193401.07652

This study compares the reactivity of side chain halogens in several benzene derivatives, including benzyl chloride, benzal chloride, benzotrichloride, benzyl bromide, and halogenated benzyl cyanides. Equimolar reactions were followed in pyridine, in benzene solution, and with sodium methylate in me…

On the Action of Tertiary Amines on Halogen-Substituted Esters

L. N. D’yakonova-Shul’ts
1934 SovietRxiv: ru-193401.07651

The study examines the reactions of a series of alpha halo-substituted esters of monobasic and dibasic acids with the tertiary amines pyridine and quinoline, with the aim of clarifying the course of addition to nitrogen. Equimolecular mixtures were reacted at room temperature or under moderate heati…

Activity of Halogens in Halogen-Substituted Ketones

B. V. Tronov, L. P. Kulev, and V. N. Orlova
1934 SovietRxiv: ru-193401.07650

The study examines the mobility of chlorine and bromine in a series of halogen-substituted ketones, with halogenated acetic esters used for comparison. The authors prepared and characterized several brominated ketones, including products from diisobutyl ketone, methylacetylacetone, and acetylacetone…

On the question of the origin of optically active compounds in nature

B. V. Tronov
1934 SovietRxiv: ru-193401.07649

This paper examines why natural organic compounds with asymmetric molecular structures are usually optically active, whereas ordinary laboratory syntheses typically yield racemic mixtures. It reviews known methods for resolving racemates and prior explanations for natural optical activity, including…

Organic Chemistry in Socialist Construction

B. V. Tronov
1934 SovietRxiv: ru-193401.07648

This article examines the development of organic chemistry and the organic chemical industry in relation to Soviet socialist construction. It contrasts earlier extractive and capitalist patterns of production with the planned Soviet aim of converting diverse carbonaceous raw materials, including coa…

Deformation of Helical Cylindrical Springs of the Simplest Type

Unknown
1934 SovietRxiv: ru-193401.07646

This article develops calculation formulas for the deformation of simple cylindrical helical springs with circular wire cross sections, addressing discrepancies between existing theory and experimental measurements. Using elementary strength of materials and energy methods, it accounts for axial for…

On the Issue of Constructing Moldboards for American Plows

G. D. Terskov
1934 SovietRxiv: ru-193401.07644

This paper examines the geometric construction of American type plow moldboards, whose rectilinear generators differ from European designs by inclining both toward the furrow bottom and the furrow wall. It derives relations among the share position, cutting angle, plane and tangent of the orthogonal…

On the Influence of Corona Discharge at Insulator Electrodes on the Safety Margin with Respect to Atmospheric Overvoltage Waves

V. K. Shcherbakov
1934 SovietRxiv: ru-193401.07643

This paper investigates whether preliminary corona discharge at insulator electrodes affects the impulse flashover strength relevant to atmospheric overvoltage waves. Using high-voltage impulse circuits, the author measures impulse discharge voltages for point electrodes, pin insulators, suspension-…

Measurement of Cos ? by the single-ammeter method

R. A. Voronov
1934 SovietRxiv: ru-193401.07642

This article proposes a simplified method for estimating the phase angle and power factor in three-phase circuits using only a single ammeter and a temporarily connected auxiliary resistance. It derives the vector relations for three current readings, under normal operation and with the same resista…

The Use of Fuel Oil from the Semi-Coking Tar of Sapropelites from the III Barzas Deposit in Diesel Engines: Parts III and IV

Unknown
1934 SovietRxiv: ru-193401.07640

This study examines the feasibility of using fuel oil derived from semi-coking tar of Barzas III sapropelites in Diesel engines, with particular attention to a Deutz-type compressorless prechamber engine and comparison with petroleum motor fuel. Through controlled engine tests, indicator diagrams, f…

Effect of Magnesium Sulfate on the Strength of Magnesia Cement

I. F. Ponomarev. M. N. Yakimov
1934 SovietRxiv: ru-193401.07632

This study examines whether magnesium sulfate in natural magnesium chloride brines from the Kulunda lakes adversely affects the strength of magnesia, or Sorel, cement. Using caustic magnesite and chemically pure magnesium chloride and sulfate, the authors prepared neat cement and 1:3 sand mixtures w…

Isothermal Evaporation of Water from the Brines of Lakes Ebeity and Kulundinskoye

M. N. Yakimov, A. A. Grigorieva, E. I. Kuminova
1934 SovietRxiv: ru-193401.07631

This study examines changes in the salt composition of natural brines from Lakes Ebeity and Kulundinskoye during isothermal evaporation at 25 degrees C. Using chemical analyses, laboratory evaporation experiments, and comparison with equilibrium diagrams for the reciprocal system involving sodium ch…

On the Production of Anhydrous Aluminum Chloride from Siberian Clays

Unknown
1934 SovietRxiv: ru-193401.07629

This study examines the feasibility of producing anhydrous aluminum chloride from West Siberian clays, motivated by the need for local raw materials for developing chemical industries. The authors analyze clays from the Nekrasovskoye and Moyskoye deposits, identify Nekrasov clay as the more suitable…

From the Editorial Board

Unknown
1934 SovietRxiv: ru-193401.07628

This editorial note introduces a collection of scientific research papers devoted to problems of practical importance for the emerging West Siberian chemical industry. It emphasizes the insufficient study of regional mineral resources, including clays and salt lakes, and points to investigations of …

Conference on New Light Sources

G. V. Spivak, B. N. Klyarfeld
1934 SovietRxiv: ru-193401.06744

From November 25 to 27, 1933, a meeting of a number of laboratories working in the field of the physics and technology of new light sources was held at the All-Union Electrotechnical Institute in Moscow.