Showing 50 of 25456 papers

On the Structure of Bindone and Its Derivatives

Unknown
1960 SovietRxiv: ru-196001.35504

This paper examines the unresolved structure and tautomeric behavior of bindone and several substituted derivatives, including bromo, nitro, methyl, oxime, isobindone, and potassium salt forms. The authors compare infrared and ultraviolet spectra and polarographic data with those of indandione-1,3 a…

Kinetics of Vapor-Phase Hydration of Ethylene over a Phosphoric Acid Catalyst

A. I. Gel'bshtein, Yu. M. Bakshi, and M. I. Temkin
1960 SovietRxiv: ru-196001.35414

The study examines the kinetics of vapor-phase hydration of ethylene to ethanol over phosphoric acid supported on silica gel under pressures and temperatures close to industrial practice. Using flow experiments with varied ethylene pressure, water pressure, contact time, catalyst grain size, and aci…

ON THE INFLUENCE OF ANION ADSORPTION ON THE PROCESS OF DISCHARGE OF HYDROGEN IONS ON PALLADIUM AND THE IONIZATION OF HYDROGEN DISSOLVED IN PALLADIUM

Unknown
1960 SovietRxiv: ru-196001.35167

This study examines how adsorption of chloride, bromide, and iodide ions affects hydrogen ion discharge on palladized palladium electrodes and the ionization of hydrogen dissolved in palladium. Using anodic charging curves and polarization measurements in acidic and alkaline electrolytes, it compare…

On a Class of Coupler Curves

I. I. ARTOBOLEVSKII
1960 SovietRxiv: ru-196001.35039

This paper examines a class of coupler curves in plane four-bar mechanisms, defined not as loci of points but as envelopes of straight lines fixed in the coupler plane. It derives the family equation for such lines, expresses the relevant geometric parameter and its derivative in terms of mechanism …

Interferometric Measurement of the Widths of the $\lambda$ $6300$ $\mathring{\mathrm{A}}$ $[\mathrm{0I}]$ and $\lambda$ $5198$ – $5200$ $\mathring{\mathrm{A}}$ $[\mathrm{NI}]$ Emissions in Auroras

T. M. MULYARCHIK
1960 SovietRxiv: ru-196001.35023

Interferometric observations at Loparskaya during winter 1958 to 1959 were used to measure Doppler widths of the forbidden auroral emissions 6300 Å [O I] and 5198 to 5200 Å [N I] with a Fabry-Perot interferometer and calibrated instrumental contours. The paper discusses the conditions under which li…

ON A NONLINEAR THEORY OF UNSTEADY SLOPE WIND

Unknown
1960 SovietRxiv: ru-196001.34932

The paper develops a nonlinear formulation for the plane unsteady wind generated above an inclined thermally homogeneous surface with prescribed time-dependent surface temperature. Assuming constant turbulent viscosity and thermal conductivity, it introduces scaled variables and represents velocity …

Integral Equations with Almost Difference Kernels

L. S. RAKOVSHCHIK
1960 SovietRxiv: ru-196001.34864

This paper studies one-dimensional integral equations in Lp spaces whose kernels are almost of difference type, represented through Fourier transforms by operator symbols depending on both position and frequency. It establishes boundedness criteria for such operators, including cases with absolutely…

Comparative hydrogenation of sodium propiolate over $\mathrm{Pt}$ , $\mathrm{Pd}$ , $\mathrm{Ni}$ catalysts

Unknown
1960 SovietRxiv: ru-196001.34823

This study compares the catalytic hydrogenation of sodium propiolate in aqueous alkaline solution over Raney nickel, platinum, and palladium catalysts at several temperatures and concentrations. Kinetic measurements, catalyst potential tracking, and polarographic analysis are used to distinguish hyd…

Radial Distribution of Atoms in a Liquid

Unknown
1960 SovietRxiv: ru-196001.34655

This paper addresses the calculation of the radial distribution function of atoms in a liquid at high density, where standard low-density correlation methods become difficult to apply. It proposes replacing the usual superposition approximation with an assumption that liquid particles may be associa…

On the State of Carbon in Liquid Cast Iron

A. A. VERTMAN and A. M. SAMARIN
1960 SovietRxiv: ru-196001.34453

This paper examines the state of carbon in liquid cast iron, addressing whether carbon is present only in solution or also as larger carbon-rich formations. The authors centrifuged molten cast iron in corundum crucibles, rapidly quenched the samples, and chemically analyzed carbon contents at the en…

The method of modules in space

B. V. Shabat
1960 SovietRxiv: ru-196001.34183

This paper extends the modulus method and its extremal length interpretation from the geometric theory of functions of one complex variable to three-dimensional Euclidean domains. It defines moduli for families of rectifiable curves and quadrable surfaces using admissible metrics, and proves distort…

ON THE CONCEPT OF A GENERALIZED SOLUTION

Unknown
1960 SovietRxiv: ru-196001.34168

The paper examines the definition of generalized solutions for quasilinear hyperbolic systems in divergence form, focusing on Gelfand’s proposal to select limits of solutions of viscous regularizations. It argues that hyperbolicity alone does not make this definition intrinsic, since the limiting di…

On densely embedded ideals of semigroups

L. N. SHEVRIN
1960 SovietRxiv: ru-196001.34156

This note studies when a semigroup can occur as a densely embedded ideal of a larger semigroup, a notion arising in the abstract characterization of transformation semigroups. After recalling annihilators and characteristic ideals, it proves that any semigroup with a nontrivial annihilator cannot be…

Equilibrium with Hydrogen and Thermodynamic Characteristics of $\mathrm{BaMoO}_4$ and $\mathrm{BaMoO}_3$

V. I. LAVRENT'EV, Ya. I. GERASIMOV, and T. N. REZUKHINA
1960 SovietRxiv: ru-196001.34104

The study investigates the equilibrium reduction of barium molybdate by hydrogen at 1200 to 1400°C as part of a broader thermodynamic analysis of molybdates. Using a circulation method and X-ray diffraction, the authors show that BaMoO4 is reduced in two stages, first forming perovskite-type BaMoO3 …

Study of the thermodynamic properties of liquid indium-bismuth alloys

N. V. ALEKSEEV, Ya. I. GERASIMOV, and A. M. EVSEEV
1960 SovietRxiv: ru-196001.33964

The thermodynamic properties of liquid indium bismuth alloys were investigated between 240 and 300°C using an electromotive force method with a molten chloride electrolyte and an indium ion concentration cell. Indium activities were calculated from measured emf values, bismuth activities were obtain…

Catalytic Oxidation of Propylene and Acrolein on a Copper Contact

V. M. BELOUSOV, Ya. B. GOROKHOVATSKII, M. Ya. RUBANIK, and A. V. GERSHINGORINA
1960 SovietRxiv: ru-196001.33938

This paper investigates the pathways by which carbon dioxide is formed during the catalytic oxidation of propylene to acrolein on copper contacts supported on carborundum. Using flow experiments under conditions intended to avoid diffusion limitations, the authors compared propylene and acrolein oxi…

Hydrolysis of $n$-nitrophenyl esters of glycine, glycylglycine, and diglycylglycine and their carbobenzoxy derivatives

Academician of the Academy of Sciences of the Tajik SSR K. T. Poroshin, Yu. I. Khurgin, and M. G. Dmitrieva
1960 SovietRxiv: ru-196001.33858

The study examines the basic hydrolysis of p-nitrophenyl esters of glycine, glycylglycine, and diglycylglycine, together with their N-carbobenzoxy derivatives, as models for activated amino acid and peptide esters in aqueous media. Hydrolysis was followed spectrophotometrically at 405 nm in a 1:1 al…

On the Mechanism of Chain Branching in the Oxidation Reaction of n-Decane

Z. K. Maizus, I. P. Skibida, and N. M. Emanuel
1960 SovietRxiv: ru-196001.33778

This paper examines the mechanism of chain branching during oxidation of n-decane, focusing on whether hydroperoxide decomposition proceeds only by monomolecular cleavage or also through bimolecular reaction with hydrocarbon molecules. Using the inhibitor method with alpha-naphthol, the authors meas…

A New Synthesis of Phytol

V. I. Gunar and S. I. Zavyalov
1960 SovietRxiv: ru-196001.33694

A synthetic route to phytol precursors and related isoprenoid compounds is described using alkylated dihydroresorcinol derivatives as starting materials. The method involves hydrolytic cleavage of 2-prenyl- and 2-geranyldihydroresorcinols to keto acids, reaction with excess methyllithium, dehydratio…

Primarily factorizable groups

Unknown
1960 SovietRxiv: ru-196001.33634

The paper studies groups in which every p-subgroup is complemented for each prime p, termed primarily factorizable groups, as a variant of fully factorizable groups. It introduces fully primitive components, p-projections, almost commutative and primary sets, and uses these notions to describe perio…

Preparation of Titanyl Oxalates of Divalent Metals and Physicochemical Study of Their Thermal Decomposition

B. V. STRIZHKOV, A. V. LAPITSKII, L. G. VLASOV, and A. I. TSVETKOV
1960 SovietRxiv: ru-196001.33614

This study describes the preparation of titanyl oxalate complex salts of divalent metals and examines their behavior during heating. Procedures were developed for obtaining barium, strontium, lead, and calcium titanyl oxalates, with calcium prepared in acetone rather than aqueous solution, and the p…

Zirconium niobate and tantalate

Academician Vikt. I. SPITSYN, L. N. KOMISSAROVA, Z. A. VLADIMIROVA,
1960 SovietRxiv: ru-196001.33506

This study examines the formation and properties of zirconium niobate and zirconium tantalate, compounds for which prior evidence was limited or absent. Mixtures of zirconium hydroxide with niobium or tantalum hydroxides were sintered at high temperature and characterized by X-ray diffraction, chemi…

On Hyperbolic Equations with Discontinuous Coefficients

Unknown
1960 SovietRxiv: ru-196001.33432

The paper studies mixed problems for second order linear hyperbolic equations with coefficients that may have jump discontinuities across prescribed surfaces, including transmission conditions for the solution and conormal derivative. Using approximation of discontinuous coefficients by smooth funct…

On the phenomenon of magnetic displacement in a free-molecular plasma flow (toward the theory of the flow around the Earth's magnetic dipole by solar corpuscular streams)

V. N. ZHIGULEV
1960 SovietRxiv: ru-196001.33411

This paper formulates the magnetic pushing-aside, or squeezing, of a collisionless fully ionized plasma stream by a body’s magnetic field when the return layer is thin compared with the interaction scale. It treats the return layer as an effective reflecting boundary, derives the pressure balance co…

On the application of the parameter variation method to the computation of eigenvalues and eigenvectors of matrices

Unknown
1960 SovietRxiv: ru-196001.33321

The paper develops a parameter variation method for computing eigenvalues and eigenvectors of a matrix whose entries depend differentiably on a parameter. Starting from a known eigenvalue at an initial parameter value, it differentiates the characteristic equation and expresses the resulting differe…

Hydrodynamic forecast of mean monthly temperature anomalies for the Northern Hemisphere of the Earth using data from the International Geophysical Year

Unknown
1960 SovietRxiv: ru-196001.33229

This paper presents a hydrodynamic method for long range forecasting of mean monthly temperature anomalies over the Northern Hemisphere using aerological data made available during the International Geophysical Year. The approach linearizes the heat inflow and vorticity equations about zonal circula…

On a theorem of V. Ponomarev

Unknown
1960 SovietRxiv: ru-196001.33021

This note strengthens a theorem of V. Ponomarev on extending open mappings to Čech compactifications by removing a compactness assumption in the single-valued case and giving a simpler proof in the multivalued setting. It proves that a continuous, closed and open mapping from a normal space onto a n…

On Critical Points of Periodic Functionals

Unknown
1960 SovietRxiv: ru-196001.33015

This paper studies critical points of functionals on the unit sphere of a Banach space that are invariant under a periodic transformation. Using Krasnosel’skii’s generalization of Lyusternik and Shnirelman category theory, it defines genus for invariant compact sets and proves the existence of sets …

On Some Interpolation Problems in the Class $H_p$ for $p<1$

V. KABAILA
1960 SovietRxiv: ru-196001.32877

This paper studies extremal interpolation in Hardy classes \(H_p\) for \(0<p<1\), extending earlier results known for \(p\geq 1\). It proves that minimal interpolating functions have the same structural form previously established for \(p\geq 1\), using a transformation that relates a minimal functi…

THE EFFECT OF RADIOLYSIS ON THE POTENTIAL OF A NICKEL ELECTRODE IN AN ALKALINE SOLUTION AS A FUNCTION OF THE COMPOSITION OF THE GAS PHASE

Unknown
1960 SovietRxiv: ru-196001.32741

This study examines how X-ray radiolysis affects the potential of a nickel electrode in 0.68 N sodium hydroxide under different gas-phase conditions, including vacuum, neon, hydrogen, and hydrogen-neon mixtures. Using a reduced nickel electrode and a mercury oxide reference electrode, the authors me…

A Method for the Synthesis of Tertiary Vinylphosphines and Their Oxides

Academician M. I. Kabachnik, Chung Jun-Noi, and E. N. Tsvetkov
1960 SovietRxiv: ru-196001.32387

A method is described for synthesizing tertiary monovinylphosphines and their oxides, compounds that had previously been little studied. The approach uses esters of secondary phosphinous acids, or in some cases vinylphosphinous acid esters, reacting with organomagnesium reagents to replace alkoxy gr…

Application of the Small Parameter Method for Constructing Solutions of Differential Equations with Delayed Argument

Yu. A. RYABOV
1960 SovietRxiv: ru-196001.32347

The paper develops a small-parameter approach for constructing solutions of differential equations with delayed argument, treating the delay as the perturbation parameter. Starting from the solution of the corresponding equation without delay, it defines successive linear approximations whose differ…

On the Heterofunctional Condensation Reaction of Bis(trimethylsiloxy)dichlorotitanium with Phenylmethyldiethoxysilane

K. A. ANDRIANOV and N. A. KURASHEVA
1960 SovietRxiv: ru-196001.32218

This paper investigates the heterofunctional condensation of bis(trimethylsiloxy)dichlorotitane with phenylmethyldiethoxysilane, and compares it with analogous reactions involving alkoxysilanes. Instead of the expected liberation of alkyl chloride and formation of simple linear polytitanorganosiloxa…

On the Interaction of Lactams with Diacetylene

M. F. SHOSTAKOVSKII, F. P. SIDELKOVSKAYA, and F. L. KOLODKIN
1960 SovietRxiv: ru-196001.32152

The study investigates the previously unreported reaction of lactams with diacetylene, using pyrrolidone as the principal example, and compares its behavior with known reactions of lactams with acetylene. The authors show that pyrrolidone adds to diacetylene under mild conditions in the presence of …

Generalized Abel Integral Equation

Unknown
1960 SovietRxiv: ru-196001.31997

The note solves a generalized Abel integral equation on a finite interval with two weakly singular one-sided integrals and variable coefficients. Using Carleman’s continuation into the complex plane, the equation is transformed into a Riemann boundary-value problem for an analytic function on the pl…