Showing 50 of 25456 papers

New Limit Theorems for Sums of Independent Random Variables

Yu. V. LINNIK
1960 SovietRxiv: ru-196001.67588

This note studies large deviation behavior for normalized sums of independent identically distributed random variables beyond the range covered by the classical central limit theorem. It defines zones of normal convergence and gives necessary and sufficient conditions, in terms of exponential moment…

Several Observations on the Chemistry of Ferrocene

A. I. TITOV, E. S. LISITSYNA, and M. R. SHEMTOVA
1960 SovietRxiv: ru-196001.67522

This paper reports preparative and reactivity observations on ferrocene and related metallocene systems, including improved synthesis of ferrocene in dioxane, preparation of a cobalticinium perbromide salt, and near quantitative oxidation of ferrocene to a ferricinium ferritetrachloride salt. The au…

On the Systematic Nature of Deviations from the Laws of Plasticity

N. M. MITROKHIN and Yu. I. YAGN
1960 SovietRxiv: ru-196001.67419

This paper examines systematic deviations from two common assumptions of plasticity under simple loading: similarity of stress and strain deviators and a unique relation between stress intensity and strain intensity independent of stress state. Experiments on annealed technically pure nickel tubular…

Fine structure of X-ray $K$-absorption spectra and the Hall effect in vanadium silicides

Z. E. VAINSTEIN, E. A. ZHURAKOVSKII, V. S. NESHPOR, and G. V. SAMSONOV
1960 SovietRxiv: ru-196001.67251

This study examines the fine structure of the vanadium K-absorption edge in the silicides V3Si, V5Si3, and VSi2, alongside Hall effect measurements, to relate electronic structure to bonding and composition. X-ray absorption spectra were compared with metallic vanadium and V2O5, while Hall coefficie…

Potential functions of molecules in the homologous series $(\mathrm{CH}_3)_n\mathrm{SiH}_{4-n}$ ( $n=1-4$ )

I. F. KOVALEV
1960 SovietRxiv: ru-196001.67236

This paper examines the potential functions of the methylsilane homologous series, from methylsilane to tetramethylsilane, with emphasis on influence coefficients that are invariant under coordinate transformations. Using a natural coordinate system, determinant calculations, earlier force-field res…

On the Spectrum of an Operator and the Dirichlet Problem for the Equation $\square^2u+4\frac{\partial^2}{\partial t^2}\square u+2\frac{\partial^4u}{\partial t^4}=f(x,y,z,t)$

Unknown
1960 SovietRxiv: ru-196001.67097

This paper studies spectral properties of operators associated with elliptic and hyperbolic fourth order equations in a four dimensional ball, formulated in Hilbert spaces defined by boundary compatible Sobolev type scalar products. It proves that the operator obtained from the inverse biharmonic op…

THERMODYNAMIC STUDIES OF 1,1-DICYCLOHEXYLDODECANE, 1,1-DIPHENYLDODECANE, AND 1-PHENYL-1-CYCLOHEXYLDODECANE AT LOW TEMPERATURES

Unknown
1960 SovietRxiv: ru-196001.67011

This study determines low temperature thermodynamic properties of 1,1-dicyclohexyldodecane, 1,1-diphenyldodecane, and 1-phenyl-1-cyclohexyldodecane under standard conditions. Purified samples were examined calorimetrically from about 12 to 320 K, with heat capacities smoothed, corrected for impurity…

Jerky motion of dislocations in $\mathrm{NaCl}$ crystals

V. N. ROZHANSKII and V. M. STEPANOVA
1960 SovietRxiv: ru-196001.66888

This paper investigates the motion of dislocations in NaCl crystals using selective etching, with emphasis on observing displacement during deformation rather than only before and after it. The authors develop a suitable etchant based on glacial acetic acid and anhydrous methyl alcohol, enabling cle…

Experimental Determination of the Enthalpy of Corundum $(\mathrm{Al}_2\mathrm{O}_3)$ at Temperatures from 500 to 2000 $^\circ$

V. A. KIRILLIN, A. E. SHEINDLIN, and V. Ya. CHEKHOVSKOI
1960 SovietRxiv: ru-196001.66803

A high-temperature calorimetric method and apparatus are described for determining the enthalpy and heat capacity of solid substances at temperatures up to about 2400°C, using a massive copper calorimeter, diathermic heat measurement, and specimen heating in vacuum or argon. The method was applied t…

On the Theory of Turbulent Combustion

A. N. VOINOV
1960 SovietRxiv: ru-196001.66724

This paper reexamines frontal theories of turbulent combustion, questioning the assumption that laminar or small scale turbulent flame fronts remain effective under arbitrary fragmentation and curvature. It argues that finite burning elements surrounded by fresh mixture can be extinguished when smal…

On the Problem of Identity in Associative Systems of a Special Type

1.** An associative system of a special kind, given by generators
1960 SovietRxiv: ru-196001.66608

The paper studies the identity problem for finitely presented associative systems whose defining relations have a special uniform form, in particular systems generated by relations of fixed word length. It proves that if the identity problem is decidable for all groups with a given number of nontriv…

2-Phenyl-4-hexafluoroisopropylideneoxazolone-5

E. M. ROKHLIN, N. P. GAMBARYAN, CHEN CHIN-YUN, and Academician I. L. KNUNYANTS
1960 SovietRxiv: ru-196001.66372

The paper describes the synthesis and reactivity of 2-phenyl-4-hexafluoroisopropylideneoxazolone-5, obtained through reactions involving hexafluoroacetone and 2-phenyloxazolone-5 or by cyclization of α-benzamidohexafluorodimethylacrylic acid. It shows that, unlike typical hexafluoroacetone adducts w…

Integral Representations

A. A. Temlyakov
1960 SovietRxiv: ru-196001.66315

The paper extends Temlyakov’s integral representation theory for analytic functions in bicircular domains of two complex variables to cases where parts of the boundary may be analytic hypersurfaces and the Levi determinant vanishes on boundary portions. By redefining the radius functions with condit…

On a Special Integral Equation with Shift

G. S. LITVINCHUK
1960 SovietRxiv: ru-196001.66210

This paper studies a singular integral equation on a closed Lyapunov contour whose Cauchy kernel contains a shift mapping the contour onto itself with reversed orientation. Under Carleman-type conditions on the shift and coefficients, the equation is transformed via the Sokhotski formulas into a bou…

Toward the Theory of Raman Scattering of Light

P. P. SHORYGIN and L. L. KRUSHINSKII
1960 SovietRxiv: ru-196001.66179

This paper examines deviations from the usual fourth-power frequency dependence of Raman line intensities as the exciting light approaches electronic absorption bands. Using both classical polarizability derivatives and a quantum expression involving vibrational sublevels of an electronic excited st…

Rule of constancy of the product of activities of simple (hydrated) metal ions and hydroxo ions in the heterogeneous system $\mathrm{M}^{n^+}-\mathrm{M(OH)}^{m^-}_{n+m}-\mathrm{M(OH)}_n-\mathrm{H}_2\mathrm{O}$

M^{n+}—M(OH)_{n+m}^{m-}—M(OH)_n—H_2O
1960 SovietRxiv: ru-196001.66016

This paper examines heterogeneous equilibria in aqueous systems containing hydrated metal ions, hydroxo complexes, solid metal hydroxide, and water, with attention to amphoteric metals that form hydroxo salts in alkaline solution. From relations between pH, hydroxide solubility, and hydroxo acid dis…

On the Embeddability of Semigroups in Groups

Unknown
1960 SovietRxiv: ru-196001.65829

This note studies when finitely presented semigroups with cancellation can be represented inside more general associative systems or groups. It gives an explicit embedding construction showing that every finitely presented semigroup with two-sided cancellation embeds in a finitely presented associat…

Modification of a Silver Catalyst with Organohalogen Compounds

Yu. N. STEPANOV, L. Ya. MARGOLIS
1960 SovietRxiv: ru-196001.65742

This paper examines how volatile organohalogen compounds modify silver catalysts used for selective oxidation of ethylene to ethylene oxide. The authors pass air or nitrogen containing various additives over silver, measure carbon dioxide formation and halide accumulation, and compare oxidation, dec…

Multidimensional moment problem

Unknown
1960 SovietRxiv: ru-196001.65480

This note studies multidimensional moment problems through positive-definite functionals on nuclear algebras of sequences and formal power series. Using an integral representation scheme for nuclear spaces, it proves representation theorems by positive measures on the real line, Euclidean spaces, an…

Study of the Hydrogen Exchange between Acetone and $\mathrm{DBr}$ in the Gas Phase by Infrared Spectroscopy

B. A. KUZNETSOV
1960 SovietRxiv: ru-196001.65258

This paper investigates hydrogen isotope exchange between acetone and deuterium bromide in the gas phase, a reaction type less studied than analogous liquid phase exchanges. Using a vacuum apparatus and infrared spectral analysis of HBr, DBr, CH, and CD bands, the study determines deuterium content,…

On the Asymptotic Behavior of Solutions of Multidimensional Systems of Ordinary Differential Equations with a Higher-Order Singular Point

A. A. SHESTAKOV
1960 SovietRxiv: ru-196001.65215

The paper studies the asymptotic behavior near a higher order singular point for analytic multidimensional systems of ordinary differential equations whose right hand sides have no constant or linear terms. Using a supporting hyperplane construction for the exponent sets, it extracts a quasihomogene…

The influence of the solvent and specific nature of the addition of nucleotides upon the reduplication of DRA

Unknown
1960 SovietRxiv: ru-196001.65180

This paper develops a statistical mechanical model of DNA reduplication that extends an earlier treatment by including solvent interactions, specificity of nucleotide attachment, and flexibility of the free DNA chains. The authors formulate the partition function for a partially separated double hel…

Measurement of the skewness coefficient of the velocity difference distribution in the atmospheric surface layer

A. S. GURVICH
1960 SovietRxiv: ru-196001.64930

This paper reports direct atmospheric measurements of the skewness coefficient of longitudinal velocity differences in the surface layer, a quantity related to Kolmogorov’s third-order structure function and to the turbulence structure constant. Using two acoustic microanemometers in open steppe ter…

On an Exact Solution of the Equations of Spatial Unsteady Gas Flow of Double-Wave Type

The system of equations of spatial unsteady motion of a polytropic gas has the form
1960 SovietRxiv: ru-196001.64542

The paper studies exact double-wave solutions of the equations for spatial unsteady motion of a polytropic gas, without assuming potential flow. Using a modified method based on common two-dimensional planar level surfaces, it reduces the governing gas-dynamic system to algebraic and differential co…

Stability of Plane-Parallel Flows of an Ideal Fluid

L. A. DIKII
1960 SovietRxiv: ru-196001.64428

This paper examines the stability of plane parallel flows of an inviscid fluid, emphasizing that the usual analysis by normal wave solutions is insufficient because such solutions need not form a complete representation of arbitrary perturbations. The author formulates and solves the Cauchy problem …

On the Coincidence of the Dimensions $\operatorname{ind}G$ and $\dim G$ for Locally Bicompact Groups

A. ARKHANGEL’SKII
1960 SovietRxiv: ru-196001.64278

This note studies dimension theory for locally bicompact topological groups, extending known results for bicompact groups. It proves first that every locally bicompact group is strongly paracompact, by exhibiting an open and closed subgroup as a countable union of bicompact sets and applying Smirnov…

Some Problems for the Operator $Lu=\operatorname{div}[p(x)\operatorname{grad}u]-q(x)u$ with Discontinuous Coefficients

In the present paper we consider the Dirichlet and Neumann problems and the eigenfunction problem for the operator
1960 SovietRxiv: ru-196001.64123

The paper studies Dirichlet, Neumann, and eigenfunction problems for the elliptic operator div[p(x) grad u] minus q(x)u in domains where the coefficients have discontinuities across internal surfaces. Under Hölder-type assumptions on the coefficients and data, positivity conditions on p and q, Lyapu…

On the Surface Properties of Highly Dispersed Quartz

L. G. GANICHENKO, M. M. EGOROV, V. F. KISELEV, K. G. KRASILNIKOV, and G. S. KHODAKOV
1960 SovietRxiv: ru-196001.64015

This study examines how grinding and dispersion affect the surface hydration and water vapor adsorption properties of highly dispersed quartz. Quartz samples prepared from the same crystalline material, with wet grinding used to reduce aggregation effects, were analyzed by water and nitrogen vapor a…

On the Mechanism of Magnesium Protection Against Oxidation

Unknown
1960 SovietRxiv: ru-196001.63620

This paper examines the mechanism by which magnesium becomes protected from oxidation and the conditions under which this protection fails. The authors argue that oxidation behavior is connected with the electronic structure of surface magnesium atoms, whose valence electrons can form exchange bonds…

Study of the Crystallization Temperatures of Bicyclo-(2,2,1)-heptadiene-2,5 and Cycloheptatriene and Their Mixtures

=========
1960 SovietRxiv: ru-196001.63515

This study determines crystallization temperatures, cryoscopic constants, and purity estimates for bicyclo-(2,2,1)-heptadiene-2,5 and cycloheptatriene, compounds relevant to aldrin production and related isomerization chemistry. Purified fractions were examined cryoscopically, including measurements…

On the Relationship Between the Growth of a Meromorphic Function and the Distribution of Its Values by Arguments

I. V. OSTROVSKII
1960 SovietRxiv: ru-196001.63514

This note studies how restrictions on the angular distribution of zeros, poles, and other value points of a meromorphic function influence its growth. Using Nevanlinna’s angular characteristics together with results of Nevanlinna, Hayman, and related growth estimates, it proves that bounded angular …

Basis tetrahedron $1/2$ $\mathrm{Li}_2\mathrm{SO}_4$ – $\mathrm{Na}\mathrm{Cl}$ – $\mathrm{RbNO}_3$ – $\mathrm{TlBr}$ in the seven-component reciprocal system $\mathrm{Li}$ , $\mathrm{Na}$ , $\mathrm{Rb}$ , $\mathrm{Tl}\parallel\mathrm{Br}$ , $\mathrm{Cl}$ , $\mathrm{NO}_3$ , $\mathrm{SO}_4$

N. S. DOMBROVSKAYA, E. A. ALEKSEEVA, N. V. KHOKHLOVA, and V. I. POSYPAIKO
1960 SovietRxiv: ru-196001.63508

This study examines the basic tetrahedron one half lithium sulfate, sodium chloride, rubidium nitrate, and thallium bromide within the seven-component reciprocal salt system Li, Na, Rb, Tl parallel Br, Cl, NO3, SO4. Fusibility measurements, heating and cooling curves, and graphical construction were…

Oxidation Reactions of Olefins

Unknown
1960 SovietRxiv: ru-196001.63476

This paper examines the oxidation of lower olefins to carbonyl compounds in aqueous systems containing divalent palladium salts, motivated by the proposed role of olefin palladium pi complexes in such transformations. The authors show that ethylene, propylene, and butenes can be oxidized using hydro…

Vl. Markov's problem for polynomials of a Chebyshev system of functions and the concept of a regular $T$-system

Unknown
1960 SovietRxiv: ru-196001.63162

This note studies the extension of Vl. Markov’s least deviation problem from ordinary algebraic polynomials to polynomials formed from Chebyshev function systems. It introduces the notion of a regular T-system, defined by a bound on the number of maximum deviation points, and distinguishes regular T…

On the Structure of 2- $n$ -Nitrophenylindane-1,3-dione

Unknown
1960 SovietRxiv: ru-196001.63140

This paper examines the origin of the unusual dark-red color and structural form of 2-p-nitrophenylindandione-1,3 in comparison with related arylindandiones. Using ultraviolet and infrared spectroscopy of the compound, its sodium salt, derivatives, and the methyl ether of its enol form, the authors …

On the Mechanism of Propellant Combustion

G. B. Manelis, A. G. Merzhanov, and F. I. Dubovitskii
1960 SovietRxiv: ru-196001.63138

This paper examines whether dispersed particles produced during combustion of pyroxylin powder burn in the hot flame zone or decompose near the burning surface. Using an isothermal estimate based on surface temperature, decomposition kinetics, gas velocity, and measured burning rates, the authors ca…