Showing 50 of 25456 papers

On the Application of Fractional Powers of Self-Adjoint Operators to the Study of Some Nonlinear Differential Equations in Hilbert Space

Unknown
1960 SovietRxiv: ru-196001.88124

The paper studies existence of solutions for nonlinear evolution equations in Hilbert space of the form v' + A(t,v)v = 0, using fractional powers of positive self-adjoint operators. It first establishes estimates and differentiability properties for the evolution operator associated with a time-depe…

On the Mechanism of the Interaction of Phenyliodoso Compounds with Certain $\beta$-Diketones

O. Ya. NEILAND and Academician of the Academy of Sciences of the Latvian SSR G. Ya. VANAG
1960 SovietRxiv: ru-196001.88117

The paper examines the reaction of phenyliodoso acetate and related phenyliodoso compounds with several beta-diketones and beta-keto esters in order to clarify the mechanism of their interaction. On the basis of product isolation, counter synthesis, and ultraviolet and infrared spectral characteriza…

Kinetics of Electrode Processes on a Silicon Electrode in Acidic and Alkaline Solutions

E. N. Paleolog, K. S. Korotkova, and N. D. Tomashov
1960 SovietRxiv: ru-196001.88082

This study examines the kinetics of hydrogen ion discharge and anodic dissolution on single crystal silicon electrodes in acidic and alkaline electrolytes, using n-type and p-type specimens of different resistivities. Polarization measurements in sulfuric acid, hydrofluoric acid, and potassium hydro…

Metal-Chemical Properties of Niobium

Unknown
1960 SovietRxiv: ru-196001.87836

This paper examines the metallochemical properties of niobium and classifies the elements of the periodic system according to their modes of interaction with it. Using electronic structure, atomic radius, electronegativity, crystal structure, melting point, and literature data on binary systems, the…

Anisotropy of the Hall Effect in Tin

V. N. KACHINSKII
1960 SovietRxiv: ru-196001.87712

This paper reports low-temperature measurements of the anisotropy of the Hall effect in high-purity single-crystal tin, motivated by the use of galvanomagnetic phenomena to probe Fermi-surface topology. At 4.2 K and magnetic fields up to about 7 kOe, the Hall-field vector was reconstructed from two …

On the Participation of the Singlet Excited State in the Electrical Conductivity of a Series of Organic Semiconductors

Unknown
1960 SovietRxiv: ru-196001.87679

This paper examines whether dark electrical conductivity in selected organic semiconductors is associated with the singlet excited state or the triplet state of the molecule. Sublimed solid layers of benzophenone, anthranilic and phenylanthranilic acids, several phthalimides, fluorescein, and severa…

Mechanism and Kinetics of the Reduction of Cobalt Oxides

V. F. BALAKIREV
1960 SovietRxiv: ru-196001.87595

This study examines the mechanism and kinetics of hydrogen reduction of cobaltous-cobaltic oxide, addressing conflicting interpretations of whether cobalt monoxide is an intermediate phase at low temperatures. Reduction experiments were conducted at 225 to 350 degrees and varied hydrogen pressures, …

Kinetic Features of Liquid-Phase Autoxidation of Isopropylxylenes

R. N. VOLKOV and S. V. ZAVGORODNII
1960 SovietRxiv: ru-196001.87512

This paper examines the liquid phase autoxidation kinetics of isopropylxylenes and related polyalkylbenzenes with adjacent alkyl substituents. Using catalytic oxidations with manganese and cobalt salts, product analysis, co-oxidation experiments, and isolation or identification of acids, alcohols, k…

Saturated vapor pressure of tetrachloroalkanes at low temperatures

N. A. MALAFEEV, V. A. MALYUSOV, N. N. UMNIK, I. V. PODGORNAYA
1960 SovietRxiv: ru-196001.87511

This paper reports measurements of the saturated vapor pressure of tetrachloroalkanes containing 9 to 17 carbon atoms at low pressures, a range needed for calculations of molecular and high-vacuum distillation processes. The authors used a static tensimetric method in which vapor force deflects a su…

Electron Density Distribution in Germanium

Academician of the Academy of Sciences of the BSSR N. N. Sirota and A. U. Sheleg
1960 SovietRxiv: ru-196001.87320

This article reports an x-ray diffraction study of the atomic scattering factor and electron-density distribution in germanium, undertaken as part of a comparative investigation of group IV semiconductor crystals. Powdered n-type single-crystal germanium was measured using Cu K alpha radiation, with…

Scattering Problem under a Nonstationary Perturbation

Unknown
1960 SovietRxiv: ru-196001.87291

This paper studies scattering of plane waves for the wave equation with a nonstationary potential in three-dimensional space, using Fock radiation conditions to characterize outgoing waves. The scattering problem is reduced to an integral equation with the retarded Green function, and existence and …

On the Behavior of Solutions of the Cauchy Problem as Time Increases Without Bound for Quasilinear Equations Arising in Combustion Theory

1.** Consider the Cauchy problem for the equation
1960 SovietRxiv: ru-196001.87177

This paper studies the large-time behavior of solutions to a Cauchy problem for a quasilinear reaction-diffusion equation arising in combustion theory, with step-like initial data and nonlinear source terms that may be nonpositive near one equilibrium and positive on part of the interval. Under spec…

Addition of $\mathrm{HGeCl}_3$ to halogen substituents of ethylene. Dehydrochlorination of $\alpha,\beta$ -dichlorethyltrichlorogermane

V. F. MIRONOV, N. G. DZHURINSKAYA
1960 SovietRxiv: ru-196001.87026

The study examines the addition of trichlorogermane to a series of chlorinated ethylenes, reactions that are difficult or low yielding for analogous chlorosilanes. Trichlorogermane was found to add readily without catalysts to vinyl chloride, dichloroethylene, trichloroethylene, and tetrachloroethyl…

INVESTIGATION OF ENERGY TRANSFER ALONG THE CHAIN $\sim\mathrm{CH}_2\sim$ BY THE METHOD OF LUMINESCENCE QUENCHING

Unknown
1960 SovietRxiv: ru-196001.86886

This paper examines whether luminescence quenching can be used to study intramolecular energy transfer along aliphatic methylene chains. A kinetic scheme is developed for gamma-excited solutions containing dioxane solvent, terphenyl activator, and alcohol quenchers, and relative light yields are use…

Radiation Oxidation of Leuco Bases in Ketones in the Absence of Oxygen

N. A. BAKH, G. G. BABICHEVA, and V. A. LARIN
1960 SovietRxiv: ru-196001.86869

This study examines whether leuco bases of triphenylmethane dyes undergo radiation oxidation in oxygen-free organic ketone solutions through products of solvent radiolysis. Nitrogen-saturated solutions, chiefly leuco crystal violet in acetone and methyl ethyl ketone, were irradiated with gamma rays,…

Thiocyanation of $2$-aryl-$1{,}3$-indandiones

Academician of the Academy of Sciences of the Latvian SSR G. Ya. Vanag, E. Yu. Gudrinietse,
1960 SovietRxiv: ru-196001.86747

This paper examines the thiocyanation of 2-arylindandiones-1,3, a previously unexplored class of thiocyanate derivatives related to pharmacologically active indandione anticoagulants. The authors prepare 2-thiocyano-2-arylindandiones by substitution of 2-bromo derivatives with potassium thiocyanate …

Temperature Dependence of the Separation Factor for the $\mathrm{C}^{13}\mathrm{O}$ – $\mathrm{C}^{12}\mathrm{O}$ System

N. N. SEVRYUGOVA and N. M. ZHAVORONKOV
1960 SovietRxiv: ru-196001.86683

The study examines the temperature dependence of the liquid vapor separation coefficient for the isotopic system C13O and C12O over a pressure range extending above atmospheric pressure. Carbon monoxide samples of natural composition and samples enriched to 23 and 32 percent C13 were purified, chara…

Ionized Gas and Fast Electrons in the Vicinity of the Earth and in Interplanetary Space

K. I. GRINGAUZ, V. G. KURT, V. I. MOROZ, and I. S. SHKLOVSKII
1960 SovietRxiv: ru-196001.86566

This paper analyzes measurements from three electrode traps on Soviet space rockets to infer ionized gas and energetic electron conditions near Earth and in interplanetary space. From collector currents and estimates of spacecraft potential, the authors argue that electron fluxes above 200 eV in the…

Iodonium derivatives of $5$-phenylcyclohexane-$1{,}3$-dione and their transformations

O. Ya. NEILAND and Academician of the Academy of Sciences of the Latvian SSR G. Ya. VANAG
1960 SovietRxiv: ru-196001.86484

This paper examines the formation, reactivity, and structural interpretation of iodonium derivatives obtained from 5-phenylcyclohexane-1,3-dione and phenyliodoso compounds. The authors prepare enolatebetaine phenyl-(5-phenylcyclohexanedione-1,3-yl-2)-iodonium and study its cleavage under acidic, bas…

Application of the Contour Integral Method to the Solution of Mixed Problems for Equations with Discontinuous Coefficients

Unknown
1960 SovietRxiv: ru-196001.86273

This paper applies the contour integral method to a mixed initial boundary value problem for second order equations with discontinuous spatial coefficients in two bounded domains separated by an interface. The argument reduces the problem to a parameter dependent spectral boundary problem, construct…

Invariant Affine Connections in Homogeneous Spaces

Unknown
1960 SovietRxiv: ru-196001.86147

This paper constructs and studies invariant torsion-free affine connections on homogeneous spaces whose motion group contains a nonmaximal equipped stationary subgroup. Using chains of equipped subgroups and associated decompositions of the Lie algebra, it derives differential equations for geodesic…

On the Triangular Representation of Certain Operators with Completely Continuous Imaginary Part

M. S. BRODSKII
1960 SovietRxiv: ru-196001.86030

This paper studies bounded Hilbert space operators whose spectrum is real and whose imaginary part is completely continuous, under an additional spectral cutting condition defining the class Omega. It constructs an ordered continuous family of invariant projections and analyzes the associated spectr…

Ferrocenesulfinic Acids

E. G. PEREVALOVA, O. A. NESMEYANOVA, and I. G. LUK’YANOVA
1960 SovietRxiv: ru-196001.85980

The study reports the synthesis and reactions of ferrocene mono- and disulfinic acids, with emphasis on preparing ferrocenedisulfinic acid by zinc reduction of the corresponding disulfonyl chloride. The authors examine the stability and solubility of the acids and sodium salts, and show that both su…

First-Order Systems Defined on a Riemannian Manifold

Unknown
1960 SovietRxiv: ru-196001.85940

The paper formulates an n-dimensional analogue of a previously studied first-order system by representing the unknowns as differential forms on a compact Riemannian manifold. It expresses the systems and their metrically adjoint counterparts using exterior differentiation and its adjoint, giving exp…

On Canonical Homogeneous Difference Schemes

Unknown
1960 SovietRxiv: ru-196001.85888

This paper studies homogeneous three-point difference schemes for one-dimensional second-order boundary-value problems with variable coefficients, focusing on canonical and conservative schemes defined through coefficient functionals. It formulates moment conditions for first- and second-order appro…

On the Coprecipitation of Trace Amounts of Germanium with Iron Hydroxide

T. I. Sendulskaya and M. Ya. Shpirt
1960 SovietRxiv: ru-196001.85759

This study examines the coprecipitation of microquantities of germanium, present as germanic acid anions, with ferric hydroxide and evaluates factors affecting its completeness. Experiments varied temperature, contact time, Ge:Fe ratio, germanium concentration, electrolyte addition, and pH, with ger…

Determination of the rate constant for the reaction of atomic oxygen with molecular hydrogen

The reaction of atomic oxygen with molecular hydrogen, with formation of hydroxyl radicals and hydrogen atoms,
1960 SovietRxiv: ru-196001.85578

This paper determines the rate constant for the elementary reaction of atomic oxygen with molecular hydrogen to form hydroxyl radicals and hydrogen atoms, a step important in oxidation mechanisms but previously lacking reliable kinetic data. The authors derive a relation between the first ignition l…

On the Reaction of Alkylcyclosiloxanes with Titanium Tetrachloride

K. A. ANDRIANOV and A. I. PETRASHKO
1960 SovietRxiv: ru-196001.85476

This paper examines the reaction of alkylcyclosiloxanes with titanium tetrachloride as a route to titanium-containing organosilicon compounds. The authors report that octamethylcyclotetrasiloxane and hexaethyltricyclosiloxane react with titanium tetrachloride above 140 degrees Celsius without added …

Construction of Non-Binary Self-Correcting Codes and Estimation of the Number of Signals in Them

V. M. OSTIANU
1960 SovietRxiv: ru-196001.85437

This paper addresses the construction and size estimation of nonbinary error-correcting codes for signals over residue classes, where correction of d symbol errors requires pairwise Hamming distance at least 2d + 1. It develops a linear coding construction for prime code bases by choosing systematic…

On the composition of singular kernels

Unknown
1960 SovietRxiv: ru-196001.85415

This paper studies the composition of singular kernels defined on a closed multidimensional Lyapunov surface in Euclidean space. Under stated size, continuity, and principal value conditions, it proves estimates for the composed kernel and for its increments, including simplified forms when one or b…

Condensation of Tetraalkylsilanes in a High-Voltage Silent Discharge at Audio Frequency

D. N. ANDREEV and E. V. KUKHARSKAYA
1960 SovietRxiv: ru-196001.85183

This study examines the condensation of trimethylethylsilane and dimethyldiethylsilane under a high-voltage silent discharge at audio frequency in hydrogen, a reaction not previously investigated for tetraalkylsilanes. The authors identify gaseous products and characterize liquid and high-boiling co…

On the Excitation of the Spin System of a Ferromagnet by a Spatially Inhomogeneous Electromagnetic Field

E. N. Yakovlev
1960 SovietRxiv: ru-196001.84987

This note examines excitation and absorption in the spin system of a Heisenberg ferromagnet subjected to a spatially inhomogeneous electromagnetic wave, a situation relevant to magneto-optical phenomena. Using linear response in terms of retarded Green functions, it derives the average rate of energ…

On Continuum Models of Control Systems

I. M. GELFAND and M. L. TSETLIN
1960 SovietRxiv: ru-196001.84894

The paper proposes a continual model of control systems intended to describe biological media more naturally than discrete automata or logical networks. It defines an active tissue whose points have instantaneous excitation, refractory time, phase-dependent propagation velocity, and possible spontan…

More on Eddy Currents in the Sea

Unknown
1960 SovietRxiv: ru-196001.84700

This paper examines the induction of alternating eddy currents in an enclosed sea during magnetic storms, motivated by earlier observations of horizontal telluric currents in the ocean. Treating the sea as shallow and circular, the author derives a simplified Maxwell-equation model for currents gene…

ON THE DISTRIBUTION OF SINGULARITIES OF ONE CLASS OF FUNCTIONS

The theorem on the distribution of singularities of one class of Dirichlet series of the form
1960 SovietRxiv: ru-196001.84591

This paper generalizes Agmon’s results on the distribution of singularities of Dirichlet series to a broader class \(B(r,h)\) of functions represented by limits of generalized Dirichlet polynomials with clustered exponents satisfying a gap condition. Using representations by divided differences and …