Showing 50 of 25456 papers

Investigation of the $\mathrm{KF}$ – $\mathrm{ZrF}_4$ system

Corresponding Member of the Academy of Sciences of the USSR A. V. NOVOSELOVA, Yu. M. KORENEV
1961 SovietRxiv: ru-196101.21938

The study examines phase relations in the potassium fluoride, zirconium fluoride system, for which earlier fusibility data did not characterize solid state transformations. Using differential thermal analysis and X-ray phase analysis, the authors constructed a phase diagram up to 75 percent zirconiu…

On the Mechanism of the Interaction of Silicon Hydrides with Organohalides in the Gas Phase

Corresponding Member of the Academy of Sciences of the USSR A. D. PETROV, E. A. CHERNYSHEV
1961 SovietRxiv: ru-196101.21856

This study examines the gas phase reaction of silicon hydrides with organic halides at high temperature, focusing on the material balance and mechanism of formation of organohalosilanes and reduction products. Experiments with chlorobenzene, chlorotoluenes, and other organohalides show that the proc…

On multipoint difference methods for solving the Cauchy problem for the equation $y'=f(x,y)$

A. D. Gorbunov, B. M. Budak
1961 SovietRxiv: ru-196101.21827

This paper studies multipoint finite difference methods for the Cauchy problem for first order ordinary differential equations, allowing implicit and explicit schemes with arbitrary numbers of points. It gives necessary and sufficient conditions for unconditional convergence under continuity and Lip…

On the exactness of limit sequences of an inverse spectrum of exact sequences of discrete groups

N. T. TYNYANSKII
1961 SovietRxiv: ru-196101.21798

This note studies when the inverse limit of an inverse spectrum of exact sequences of discrete Abelian groups remains exact, rather than only semi-exact. For spectra indexed by a directed set with a countable cofinal subset, it proves sufficient epimorphism conditions on the bonding homomorphisms, f…

THE INFLUENCE OF DISSOLVED TEMPLATES ON THE FORMATION OF SPECIFIC ADSORPTION PROPERTIES OF THE SURFACE OF SILICA GELS

Unknown
1961 SovietRxiv: ru-196101.21669

This study examines how dissolved azo dye templates influence the development of selective adsorption properties in silica gels, with particular attention to whether nonextractable template dye is responsible for specificity. Silica gels were prepared with methyl orange, ethyl orange, propyl orange,…

On a New Analogy in Mechanics

Unknown
1961 SovietRxiv: ru-196101.21625

This paper establishes an analogy between plane potential flow of an ideal incompressible fluid and the plane trajectory problem for a material point in a conservative field at fixed energy. Starting from Jacobi’s least action principle, it derives a trajectory equation in terms of the logarithm of …

On a problem generalizing the Carleman boundary value problem

G. S. LITVINCHUK
1961 SovietRxiv: ru-196101.21497

The paper studies a boundary value problem for piecewise analytic functions on a Lyapunov contour, involving values at a point and at its image under an orientation reversing involution, as a generalization of the Carleman problem. Under Hölder and compatibility assumptions on the coefficients, the …

THE PROBLEM OF INELASTIC SCATTERING

It is required to find a solution of the infinite system of equations
1961 SovietRxiv: ru-196101.21479

The paper studies the mathematical problem of inelastic scattering represented by an infinite system of coupled Helmholtz equations in three-dimensional space, with outgoing radiation conditions for elastic and inelastic scattered waves. It reformulates the system as an operator equation in the Hilb…

On distortion under quasiconformal mappings

V. GAVRILOV
1961 SovietRxiv: ru-196101.21384

This note studies distortion estimates for quasiconformal mappings of the unit disk and for Ahlfors classes of quasiconformal mappings in the mean. Using a recent improved bound for the Teichmüller function, it refines Lavrent’ev’s modulus distortion theorem to a sharp two-sided estimate for distanc…

On the Complexity of Superpositions in Bases Containing Nontrivial Linear Formulas with Zero Weights

Unknown
1961 SovietRxiv: ru-196101.21376

The paper studies the asymptotic complexity of representing Boolean functions by formulas over bases that include nontrivial linear formulas of zero weight, together with conjunction and, when needed, negation of unit weight. Using Post’s classification of closed classes of linear Boolean functions,…

Toward the Study of the Kinetics of Substitution Reactions in the Inner Sphere of Complex Molecules

A. D. GELMAN and L. N. ESSEN
1961 SovietRxiv: ru-196101.21302

This study examines the kinetics of inner-sphere substitution reactions of potassium triacidomonoammineplatinates of divalent platinum with pyridine in aqueous solution. Rate constants were determined at several reactant concentrations and for freshly prepared and aged solutions, with accompanying p…

$o$-$(2,3 (\mathrm{CO}), 6,5 (\mathrm{CO})$-dibenzoyleneisonicotinoyl)benzoic acid

G. Ya. DUBUR and Academician of the Latvian SSR G. Ya. VANAG
1961 SovietRxiv: ru-196101.21182

This paper investigates the reaction of oxytrisindandione and related spiro-dihydropyridine derivatives as routes to o-(2,3(CO),6,5(CO)-dibenzoylenisonicotinoyl)benzoic acid and its derivatives. The authors show that treatment of oxytrisindandione with ammonium acetate in glacial acetic acid, or oxi…

NITRATE ESTERS OF C-SUBSTITUTED CARBOHYDRATES

Unknown
1961 SovietRxiv: ru-196101.20936

This paper reports the synthesis of nitrate esters of several C-substituted carbohydrates, motivated by the pharmacological interest of nitrate esters of polyhydroxy compounds as vasodilators. The authors applied nitration with fuming nitric acid in acetic anhydride to glucopyranosyl-, galactopyrano…

Quadratic mean and arithmetic mean

B. S. STECHKIN and S. B. STECHKIN
1961 SovietRxiv: ru-196101.20883

This note proves an identity expressing the L2 norm squared of a function on the unit interval as an infinite sum of squares of L1 means generated by a simple iterative procedure. Starting with a function y, the authors define successive functions by subtracting from the absolute value of the preced…

Decay of the Two-Hour Isotope $\mathrm{Lu}^{168}$

E. P. GRIGOR’EV, K. Ya. GROMOV, Corresponding Member of the USSR Academy of Sciences B. S. DZHELEPOV,
1961 SovietRxiv: ru-196101.20803

The paper investigates the decay of a previously observed approximately two-hour lutetium activity produced by irradiating tantalum with 660 MeV protons. Using a calibrated double-focusing beta spectrometer, the authors measure internal conversion lines and identify an 87.54 keV transition in the da…

On the Mechanism of Radiolysis Inhibition

A. M. BRODSKII and Yu. A. KOLBANOVSKII
1961 SovietRxiv: ru-196101.20728

This paper develops a mechanism for the inhibition of radiolysis in organic systems by small concentrations of impurities, treating inhibition as direct transfer of electronic excitation from an irradiated molecule, ion, or radical to an inhibitor molecule. Using a dipole approximation and a quantum…

Study of the Surface of an Iron Electrode by Measuring the Potential Decay After Current Interruption

V. V. SOBOL and Z. A. IOFA
1961 SovietRxiv: ru-196101.20727

This study examines the surface state of iron electrodes by calculating capacitance from potential decay after interruption of cathodic polarization current. Using loop and electronic oscillographs, the authors measured decay curves for iron in alkaline and acidic solutions, including electrodes poi…

On Projective Embeddings of Algebraic Varieties

B. G. Moishezon
1961 SovietRxiv: ru-196101.20701

This paper formulates an algebraic-geometric analogue of Kodaira’s projective embedding theorem for nonsingular complete abstract algebraic varieties over an algebraically closed field of characteristic zero. It proves that if a divisor has positive top self-intersection and positive intersection wi…

On the Thermal Condensation of Dichlorosilane with Chlorobenzene

K. A. ANDRIANOV, V. I. SAVUSHKINA, S. A. GOLUBTSOV, and B. A. CHARSKAYA
1961 SovietRxiv: ru-196101.20652

The study examines the thermal condensation of dichlorosilane with chlorobenzene and shows that the reaction is more complex than the simple formation of phenyldichlorosilane. Experiments in a heated quartz tube, followed by fractional distillation and product analysis, were used to determine how te…

Luo Chih-hsiang, E. M. Savitskaya, and B. P. Bruns

Unknown
1961 SovietRxiv: ru-196101.20647

This study examines how water and methanol mixtures affect the acid properties of a carboxylic cation exchanger obtained by saponification of a methyl methacrylate and divinylbenzene copolymer. Potentiometric titration was used, including a rapid method based on partially neutralized resin samples t…

Thermodynamic and Diffusion Characteristics of Silicate Components of Cement during Their Dissolution in Water

Unknown
1961 SovietRxiv: ru-196101.20640

This paper investigates the metastable solubility and diffusion characteristics of tricalcium silicate and beta-dicalcium silicate in water, parameters considered important for understanding cement stone hardening. The authors determine solubility by several independent approaches, including rotatin…

Radiocarbon Age of Some Quaternary Samples

I. E. Starik and Kh. A. Arslanov
1961 SovietRxiv: ru-196101.20545

This paper reports radiocarbon dating of Quaternary peat, wood, gyttja, and related deposits from the European part of the USSR using a scintillation method based on synthesized benzene or ethylbenzene. The authors compare the obtained ages with stratigraphic and spore-pollen interpretations for Hol…

On the approximation of functions from the spaces $\widetilde{W}_p^{(l)}(D)$ and $W_p^{(l)}(D)$ by continuously differentiable functions

V. P. IL’IN
1961 SovietRxiv: ru-196101.20534

The paper studies approximation in Sobolev and Slobodetskii type spaces on domains of Euclidean space, focusing on when functions in the spaces defined by highest order generalized derivatives can be approximated in the corresponding norms by functions smooth in the whole space. It introduces geomet…

On the Problem of Gluing Two Semicircles

D. B. POTYAGAILO
1961 SovietRxiv: ru-196101.20468

The paper studies the type problem for Riemann surfaces associated with gluing two half-disks, reformulated in terms of gluing two half-strips by a prescribed boundary homeomorphism. It constructs a class of simply connected Riemann surfaces with first-order algebraic branch points, decomposed into …

SEPARATION OF FREE RADICALS BY PAPER CHROMATOGRAPHY

![Fig. 1. E.p.r. spectrum of the primary Ionol radical](image)
1961 SovietRxiv: ru-196101.20336

This paper addresses the difficulty of interpreting electron paramagnetic resonance spectra of oxidized alkyl-substituted phenols when primary and secondary stable radicals are present simultaneously. Using paper chromatography, especially elution with 96 percent ethanol, the authors separated radic…

Higher approximations in averaging

Unknown
1961 SovietRxiv: ru-196101.20269

This paper studies higher order averaging for singularly perturbed systems with slow variables and fast degenerate motion whose trajectories admit uniform mean values. It formulates a second approximation averaged system, constructed through characteristic equations and auxiliary correction function…

Faradaic impedance for reversible electrode processes proceeding according to the catalytic hydrogen evolution scheme

V. G. Levich, B. I. Khaikin, and V. A. Kir’yanov
1961 SovietRxiv: ru-196101.20225

This paper derives relations for the Faradaic impedance of a reversible electrode process following a catalytic hydrogen evolution scheme in which a catalyst undergoes protolytic interconversion, reversible electrochemical discharge, and bimolecular regeneration with hydrogen formation. Using diffus…

Modules over a $K$-space

S. N. Slugin
1961 SovietRxiv: ru-196101.20185

This paper develops a theory of modules over a \(K\)-space with unit, treating the \(K\)-space as a generalized scalar ring and using suitable notions of quotient, convergence, norm, and scalar product. It defines generalized \(M_Z\)-modules, normed \(B_Z\)-modules, and inner product \(H_Z\)-modules…

On a Representation of a Tensor Function

V. D. BONDAR
1961 SovietRxiv: ru-196101.20132

The paper develops a representation of tensor functions by extending the Pfaffian form representation of vector fields. Using canonical forms of Pfaffian forms, it derives general formulas for vector components in n-dimensional space and applies them to tensor functions viewed as vectors in the spac…

Thermodynamic Properties of $\mathrm{Ag}$ – $\mathrm{Bi}$ Melts

As a result of studying the electromotive forces (e.m.f.) of galvanic cells:
1961 SovietRxiv: ru-196101.20104

The paper reports thermodynamic measurements of liquid silver, bismuth alloys at 1000 K using electromotive forces of galvanic cells with an iodide molten electrolyte over 650 to 850 °C and varying alloy compositions. From the temperature and composition dependence of the cell potentials, the author…

Synthesis and Chemistry of Nitroallyl

Unknown
1961 SovietRxiv: ru-196101.20043

This paper investigates new routes to nitroallyl, an intermediate for polynitro compound synthesis, and examines its subsequent chemical transformations. The authors report that allyl bromide and allyl iodide react with nitrogen tetroxide in ether at low temperature to give nitroallyl in useful yiel…

Quadrupole absorption coefficient and optical lifetime of the exciton ground state in $\mathrm{Cu}_2\mathrm{O}$ crystal

Unknown
1961 SovietRxiv: ru-196101.19951

This paper reports a quantitative study of the anisotropic absorption of the 6125 Å exciton line in cuprous oxide at 77 K, associated with excitation of the ground exciton state. Absorption coefficients were measured for light propagation along the fourth-order and third-order symmetry axes of singl…

Synthesis and spectra of deuteronitroform

Unknown
1961 SovietRxiv: ru-196101.19704

Deuteronitroform was prepared as a labeled analogue of nitroform for use in studying addition reactions and tautomeric transformations of acinitroalkanes. The synthesis involved treatment of the potassium salt of trinitromethane suspended in dry methylene chloride with dry deuterium chloride, giving…

On the Application of Radar to Studying Cloud Structure

Unknown
1961 SovietRxiv: ru-196101.19400

This paper examines whether radar echoes from clouds can be used to infer cloud liquid water content and boundaries. Using simultaneous radar and aircraft observations conducted in 1959 and 1960, the authors compare measured radar reflectivity with direct microphysical measurements and find no stabl…

Arylalkylation of Anisole with Styrene and $\alpha$-Methylstyrene in the Presence of $\mathrm{BF}_3\cdot\mathrm{H}_3\mathrm{PO}_4$ and $\mathrm{BF}_3\cdot\mathrm{O}(\mathrm{C}_2\mathrm{H}_5)_2$

S. V. ZAVGORODNII and E. V. ALISOVA
1961 SovietRxiv: ru-196101.19396

The study examines arylalkylation of anisole with styrene and alpha-methylstyrene using boron fluoride phosphoric acid and boron fluoride ethyl etherate catalysts, a reaction type previously little investigated for alkyl phenyl ethers. Experiments varied catalyst, reactant ratios, temperature, and t…

Kinetics of Carbon Surface Growth during Thermal Decomposition of Methane in the Temperature Range $1400-1700^\circ$ C

Unknown
1961 SovietRxiv: ru-196101.19338

The paper investigates the kinetics of carbon surface growth during thermal decomposition of methane in hydrogen at 1400 to 1700°C, a range where earlier measurements were suspected to be affected by diffusion. Carbon film growth was measured on graphite rods in a high-temperature furnace at methane…

Reaction of Triethylsilane with Acetylenic $\gamma$-Glycols in the Presence of $\mathrm{Pt}/\mathrm{C}$ and $\mathrm{H}_2\mathrm{PtCl}_6$

I. M. GVARDTSITELI, K. I. CHERKEZISHVILI
1961 SovietRxiv: ru-196101.19216

This study examines the reactions of triethylsilane with primary, secondary, and tertiary acetylenic gamma glycols in the presence of platinum on carbon and chloroplatinic acid catalysts. The authors compare reaction pathways and products, showing that catalyst type and glycol substitution influence…

The Galois group of a local field

HELMUT KOCH
1961 SovietRxiv: ru-196101.19084

The paper studies the structure of Galois groups associated with local fields, focusing first on regular finite extensions of the p-adic numbers and on maximal normal p-extensions over a finite regular extension without higher ramification. It gives an explicit presentation of the resulting Galois g…