Showing 50 of 25456 papers

Polarization curves for electrodes partially immersed in an electrolyte solution

Corresponding Member of the Academy of Sciences of the USSR V. G. Levich, Yu. A. Chizmadzhev,
1964 SovietRxiv: ru-196401.03505

This paper develops a theoretical description of polarization curves for smooth electrodes partially immersed in an electrolyte, motivated by their relevance to gas porous electrode processes. Considering hydrogen diffusion through an electrolyte film followed by electrochemical discharge, the autho…

Radiolysis of Aqueous Ferrous Sulfate Solutions Induced by Decimicrosecond Electron Pulses

A. K. PIKAEV, P. Ya. GLAZUNOV
1964 SovietRxiv: ru-196401.03470

The study examines the radiolysis of aerated and oxygenated aqueous ferrous sulfate solutions in sulfuric acid under decimicrosecond electron pulses, with attention to how high absorbed dose rates affect ferric ion formation and oxygen consumption. Electron pulses of about 6 · 10^-7 s were generated…

Radiation Synthesis of Polymers Based on Trimeric Cyclic Dimethylphosphinoborine

A. I. SOLOMATINA, Yu. G. CHIKISHEV, B. L. TSETLIN, S. R. RAFIKOV,
1964 SovietRxiv: ru-196401.03395

This study examines the radiation-induced polymerization of trimeric cyclic dimethylphosphinoborine, motivated by the expected stability of polycyclic phosphinoborine structures and analogies with borazole polymerization. The monomer was irradiated with 800 kV electrons in sealed evacuated ampoules …

ON THE SPECTRUM OF A REGULAR QUASI-DIFFERENTIAL OPERATOR

Unknown
1964 SovietRxiv: ru-196401.03097

This note studies the spectral properties of regular quasi-differential operators in L2(a,b), generally non-self-adjoint, defined by a self-adjoint quasi-differential expression and linearly independent boundary conditions. It introduces a normalized Wronskian determinant formed from solutions satis…

Hydrazinolysis – a New Method for Studying the Structure of Nitrogen-Containing Polymers with Conjugated Bonds

B. E. DAVYDOV, Yu. V. KORSHAK, B. A. KRENTSEL
1964 SovietRxiv: ru-196401.03044

This paper examines hydrazinolysis as a chemical method for investigating insoluble and infusible nitrogen-containing polymers with conjugated bonds, particularly systems in which infrared spectroscopy cannot distinguish the relative roles of C=C and C=N bonds. The authors treat polyazines, poly-Sch…

Dependence of Hydrogen Chemisorption at the Metal–Solution Interface on the pH of the Solution

Yu. M. TYURIN, A. M. TSYBULEVSKAYA
1964 SovietRxiv: ru-196401.03009

This paper examines how solution pH affects hydrogen chemisorption at the rhodium solution interface, using charge curves for compact rhodium and previously obtained data for rhodium black in sulfuric acid solutions at constant sulfate concentration. By superposing charge curves and analyzing potent…

On the acid-base properties of complex compounds of platinum(II) containing $\alpha$-methylhydroxylamine

Unknown
1964 SovietRxiv: ru-196401.02605

This study examines whether proton dissociation in divalent platinum complexes containing coordinated hydroxylamine occurs from the amido group or the hydroxo group. Cis and trans isomers of diamminobis(alpha-methylhydroxylamine)platinum(II) chloride were synthesized and characterized by elemental a…

ON THE GROUP OF AUTOMATIC ONE-TO-ONE MAPPINGS

Unknown
1964 SovietRxiv: ru-196401.02596

This paper studies groups formed by one-to-one mappings of the set of words over a finite alphabet that are induced by finite automata. It characterizes such automatic mappings as length-preserving permutations compatible with initial segments, shows that the full set of automatic bijections is a su…

THE ROLE OF THE H-BOND IN THE PROCESSES OF DEACTIVATION OF EXCITED ELECTRONIC STATES OF MOLECULES LEADING TO THE FORMATION OF RADICALS

D. N. Shigorin, A. K. Piskunov, G. A. Ozerova, N. A. Shcheglova, N. V. Verein
1964 SovietRxiv: ru-196401.02516

This study examines how hydrogen-bonded complexes influence the deactivation of excited electronic states and radical formation in molecules containing carbonyl or nitrogen chromophoric groups. Luminescence, infrared, and EPR spectra were measured for anthraquinone, acridone, aromatic amine derivati…

Singular elliptic equations and systems of variable order

M. I. VISHIK, G. I. ESKIN
1964 SovietRxiv: ru-196401.02359

The paper develops a theory of singular elliptic equations and systems whose symbols have variable order on closed manifolds and bounded domains with smooth boundary. It introduces Sobolev-type spaces of variable smoothness, proves compact embedding properties, and establishes Fredholm, or Phi-opera…

On a Parametric Representation of Some General Classes of Meromorphic Functions in the Unit Disk

Academician of the Academy of Sciences of the Armenian SSR M. M. DZHRBASHYAN
1964 SovietRxiv: ru-196401.02250

The paper extends Nevanlinna’s parametric representation theorem for meromorphic functions of bounded characteristic in the unit disk to a one-parameter family of broader classes. Using Riemann-Liouville fractional integrals and derivatives, it defines an alpha-characteristic for meromorphic functio…

New lead-containing perovskite compounds of complex composition

Yu. N. VENEṬSEV, Yu. E. ROGINSKAYA, A. S. VISKOV, V. V. IVANOVA,
1964 SovietRxiv: ru-196401.02084

This paper reports the targeted synthesis and X-ray characterization of new lead-containing perovskites of complex composition, selected using crystal-chemical constraints, electroneutrality, and a tolerance factor near unity. Ceramic samples containing two or three different B-site ions were fired …

Criterion for the Finiteness of the Number of Discrete Levels Introduced into the Gaps of the Continuous Spectrum by Perturbations of a Periodic Potential

It is known that the spectrum of the problems
1964 SovietRxiv: ru-196401.02068

This paper studies the one-dimensional Schrödinger equation with a real periodic potential under a real nonperiodic perturbation that decays sufficiently fast at infinity. It addresses when such a perturbation can introduce only finitely many discrete eigenvalues into each gap of the continuous spec…

Macroscopic description of kinetic processes

A. M. KOGAN, L. I. ROZONOER
1964 SovietRxiv: ru-196401.02020

The paper proposes a general scheme for macroscopic descriptions of kinetic processes when slow variables, including nonequilibrium relaxing quantities such as heat flux or viscous stresses, are treated as independent. Starting from a phase-space cell representation and an intermediate mixing assump…

Stationary Resonant Modes of Some Oscillatory Systems

Unknown
1964 SovietRxiv: ru-196401.01998

This paper studies stationary resonance regimes in one degree of freedom oscillatory systems with slowly varying parameters and a small nonlinear perturbation that is periodic in time. Using variables defined by the extrema and phase of the unperturbed motion, the authors derive averaged equations n…

Synthesis of Polyesters Containing Triple Bonds in the Chain

A. G. MAKHSUMOV
1964 SovietRxiv: ru-196401.01720

This study examines the synthesis of polyesters containing conjugated triple bonds by joint oxidative dehydropolycondensation of propargyl and dipropargyl esters with p-diethynylbenzene. The authors selected aromatic, bisphenol, fluorinated bisphenol, benzoate, phenoxy, and quinizarin derivatives to…

A New Variational Formalism in General Relativity

K. P. STANYUKOVICH
1964 SovietRxiv: ru-196401.01241

The paper proposes a variational reformulation of general relativity motivated by dimensional transformation arguments, claiming that the standard Einstein equations with constant gravitational coupling do not transform consistently under changes of distance and therefore are inadequate for the meta…

On the Mechanism of Reactions of Esters of Trivalent Phosphorus Acids with Silicon and Tin Alkyl Halides

A. N. Pudovik, A. A. Muratova
1964 SovietRxiv: ru-196401.01192

This paper examines the mechanism of reactions between esters of trivalent phosphorus acids and alkyl halides of silicon and tin, reactions known to yield products containing P-O-Si or P-O-Sn bonds rather than the usual Arbuzov products. Using ethyl diethylphosphinite with trialkylchlorosilanes and …

On the mechanism of diene polymerization under the influence of complex catalysts based on cobalt compounds

L. S. Bresler, E. N. Kropacheva, I. Ya. Poddubnyi, V. N. Sokolov
1964 SovietRxiv: ru-196401.01138

This paper examines the mechanism of diene polymerization initiated by complex cobalt catalysts, addressing conflicting interpretations obtained from deactivation of growing chains with isotopically labeled alcohols. The authors compare cobalt systems with reference anionic, cationic, and coordinati…

Synthesis of Semisymmetric Tris-Amides of Boric Acid

Ya. M. Paushkin, I. S. Panidi, L. A. Platonova
1964 SovietRxiv: ru-196401.00941

This paper examines the preparation of semisymmetric tris-amides of boric acid by transamination of tris(dimethylamino)boron and tris(diethylamino)boron with aliphatic and aromatic amines. The authors argue that the greater reactivity of the dimethylamino derivative limits its use with lower aliphat…

Bimetallic Derivatives of Chromium, Molybdenum, and Tungsten Carbonyls

A. N. NESMEYANOV, K. N. ANISIMOV, N. E. KOLOBOVA, M. Ya. ZAKHAROVA
1964 SovietRxiv: ru-196401.00801

This paper reports the synthesis and characterization of mixed bimetallic derivatives of chromium, molybdenum, and tungsten carbonyls containing tin or lead substituents. Sodium salts of tricarbonyl pi-cyclopentadienyl metal carbonyls were reacted with triphenyltin, triphenyllead, or diphenyltin chl…

Mechanism of Methane Steam Reforming Reactions

Unknown
1964 SovietRxiv: ru-196401.00664

This paper examines the reaction mechanism of methane conversion with steam to produce synthesis gas, focusing on limitations in earlier schemes that combined methane thermal decomposition with subsequent reactions of its products. Using literature thermochemical data, bond dissociation energies, an…

Determination of the Principal Indices of Laurent Series

I. V. VITENKO, A. N. KOSTOVSKII
1964 SovietRxiv: ru-196401.00576

This note studies the determination of principal indices of Laurent series convergent in an annulus, extending earlier criteria known for polynomials and related sufficient conditions. The authors introduce transformed Laurent series formed from products over roots of unity and define coefficient ra…

Studies of the Thermodynamic Properties of Gallium Tellurides by the Electromotive Force Method

Ya. I. GERASIMOV, V. P. VASIL’EV
1964 SovietRxiv: ru-196401.00498

The study examines the thermodynamic properties and phase behavior of gallium tellurides in the gallium tellurium system, with particular attention to Ga2Te3, GaTe, and the proposed tellurium-rich GaTe3 phase. Concentration electrochemical cells with liquid gallium and solid gallium tellurium alloys…

Autohesion of Polyethylene Under High Pressure

R. A. BALTĖNAS, L. A. IGONIN
1964 SovietRxiv: ru-196401.00435

This study examines the autohesion of two polyethylenes with different degrees of branching and molecular order under pressures up to 6000 kg/cm2 and temperatures up to 240 C. Paired specimens were pressed, cooled, and torn apart perpendicular to the contact surface, with tear-off stress used as a m…

Singular Integral Equations on an Infinite Cylinder

Unknown
1964 SovietRxiv: ru-196401.00406

This paper develops a theory of singular integral equations on an infinite multidimensional cylinder, modeled as a strip with periodic variables and unbounded Euclidean variables. It introduces an appropriate Fourier transform, constructs periodic singular kernels in the Calderón and Zygmund setting…

Kinetic Characteristics of the Decomposition of Peroxide Compounds in Irradiated DNA Solutions

G. P. Zhizhina, D. L. Zybina, K. E. Kruglyakova,
1964 SovietRxiv: ru-196401.00296

This study examines the decomposition kinetics of peroxide compounds formed in aqueous DNA solutions after X-ray irradiation, with attention to their possible role in radiation aftereffects. Using spectrophotometric determination of hydroperoxides at different temperatures, the authors show that dec…

The promotion of a skeleton nickel catalyst by molybdenum

T. KABIEV, A. B. FASMAN, N. I. MOLYUKOVA,
1964 SovietRxiv: ru-196401.00243

This study examines the promotion of skeleton nickel catalysts by molybdenum introduced into Ni-Al alloys for liquid-phase hydrogenation of o-nitrophenol, potassium maleate, and allyl alcohol. Reaction rates and catalyst potentials were measured simultaneously after alkaline leaching of alloys with …

Effect of Collisions on Drift Instability in a Plasma with a Finite Ion Larmor Radius

A. B. MIKHAILOVSKII, O. P. POGUTSE
1964 SovietRxiv: ru-196401.00055

This paper examines how particle collisions affect drift instability in an inhomogeneous low-pressure plasma when the ion Larmor radius is finite. It proposes using a Bhatnagar, Gross, and Krook model collision term to extend the method of integration along trajectories to collisional plasma oscilla…

On a Two-Layer Thermoconvective Problem

N. A. AVDONIN
1963 SovietRxiv: ru-196301.99745

This paper studies a two-layer thermoconvective boundary value problem motivated by heat propagation in a reservoir under thermal injection, with vertical heat conduction in both layers and horizontal convection in one layer. After a change of variables, the problem is formulated through Green funct…

On $\omega$-mappings and inverse spectra

All spaces considered below are assumed to be Hausdorff, and the mappings continuous.
1963 SovietRxiv: ru-196301.99731

This paper studies inverse spectra and classes of Hausdorff spaces characterized by mappings subordinate to open covers, especially omega-mappings and weak omega-mappings. It proves dimension-preserving factorization and spectral representation results, showing, for example, that normal finite-dimen…

ON THE PROBLEM OF SOLVING THE COAGULATION EQUATION FOR RAIN DROPS WITH CONDENSATION TAKEN INTO ACCOUNT

Unknown
1963 SovietRxiv: ru-196301.99600

This paper examines the evolution of the size spectrum of rain drops in an ascending air current when both coagulation and condensational growth are considered. Assuming a collision probability proportional to the sum of the colliding drop volumes, the kinetic coagulation equation is transformed by …